Cobalt-catalyzed regio- and stereoselective intermolecular enyne coupling: an efficient route to 1,3-diene derivatives

被引：61
作者：
Mannathan, Subramaniyan [1 ]
Cheng, Chien-Hong [1 ]
机构：
[1] Natl Tsing Hua Univ, Dept Chem, Hsinchu 30013, Taiwan
来源：
CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 11期
关键词：
ACTIVATED ALKENES; NICKEL-COMPLEXES; ALKYNES; CYCLOADDITION; CYCLOISOMERIZATION; CODIMERIZATION; CYCLIZATION; ACETYLENES; N-ENYNES; ALLENES;
D O I：
10.1039/b920071a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The reaction of alkynes with vinyl arenes or vinyl trimethyl silane in the presence of a cobalt(II) complex, Zn and ZnI(2) in CH(2)Cl(2) at rt to 50 degrees C provides 1,3-dienes in good to excellent yields.
引用
收藏
页码：1923 / 1925
页数：3
相关论文
共 41 条
  • [1] The behavior of 1,n-enynes in the presence of transition metals
    Aubert, C
    Buisine, O
    Malacria, M
    [J]. CHEMICAL REVIEWS, 2002, 102 (03) : 813 - 834
  • [2] Cobalt-catalyzed reductive coupling of activated alkenes with alkynes
    Chang, Hong-Tai
    Jayanth, Thiruvellore Thatai
    Wang, Chun-Chih
    Cheng, Chien-Hong
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (39) : 12032 - 12041
  • [3] Cobalt-catalyzed diastereoselective reductive [3+2] cycloaddition of allenes and enones
    Chang, Hong-Tai
    Jayanth, Thiruvellore Thatai
    Cheng, Chien-Hong
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (14) : 4166 - +
  • [4] Synthesis of dihydronaphthalenes via Aryne Diels-Alder reactions: Scope and diastereoselectivity
    Dockendorff, C
    Sahli, S
    Olsen, M
    Milhau, L
    Lautens, M
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (43) : 15028 - 15029
  • [5] HOMO-DIELS-ALDER CYCLOADDITIONS CATALYZED BY COBALT TRIPHENYLPHOSPHINE ZINC SYSTEMS
    DUAN, IF
    CHENG, CH
    SHAW, JS
    CHENG, SS
    LIOU, KF
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (19) : 1347 - 1348
  • [6] Grotjahn D.B., 1995, COMPREHENSIVE ORGANO, V12, P741
  • [7] Catalytic intermolecular reductive coupling of enones and alkynes
    Herath, Ananda
    Thompson, Benjamin B.
    Montgomery, John
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (28) : 8712 - +
  • [8] Hilt G., 2007, ANGEW CHEM, V119, P8653
  • [9] Cobalt-catalyzed Alder-ene reaction
    Hilt, Gerhard
    Treutwein, Jonas
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (44) : 8500 - 8502
  • [10] Huang DJ, 2000, CHEM-EUR J, V6, P3706, DOI 10.1002/1521-3765(20001016)6:20<3706::AID-CHEM3706>3.0.CO
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