Characterization of Oxide Scales Formed on Ferritic Stainless Steel 441 at 1,100 A°C under water vapor

被引：19
作者：
Badin, Valentin [1 ]
Diamanti, Entela [2 ]
Foret, Pierre [2 ]
Darque-Ceretti, Evelyne [1 ]
机构：
[1] PSL Res Univ, CNRS UMR 7635, CEMEF Ctr Mat Forming, MINES ParisTech, F-06904 Sophia Antipolis, France
[2] Linde AG, D-85716 Unterschleissheim, Germany
来源：
OXIDATION OF METALS | 2014年 / 82卷 / 5-6期
关键词：
Ferritic stainless steel; Oxidation; High temperature; Short-term exposures; Water vapor; OXIDATION BEHAVIOR; ATMOSPHERES; ALLOYS; AIR; ENVIRONMENT; EVAPORATION; CHROMIUM;
D O I：
10.1007/s11085-014-9495-2
中图分类号：
TF [冶金工业];
学科分类号：
0806 ;
摘要：
This study focuses on the characterization of the oxide scales formed after different exposure times in the range of 2.5-20 min. A commercially available ferritic steel grade AISI 441 was exposed to wet argon at 1100 A degrees C with 5, 9 and 13% H2O. Raman microspectroscopy, XRD, EDS and XPS were used to fully characterize the oxide scale. For all samples exposed for over 4 min, the scale was constituted of three layers in this order: a thin top layer of spinel phases (Fe,Cr,Mn)(3)O-4 with local outgrowths; a second and main layer of Cr2O3 + (Mn,Cr)(3)O-4; and finally a bottom layer of SiO2. The uncommon presence of Fe in the top layer was also observed.
引用
收藏
页码：347 / 357
页数：11
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