Characterization of Oxide Scales Formed on Ferritic Stainless Steel 441 at 1,100 A°C under water vapor

被引：19

作者：

Badin, Valentin ^{[1
]}

Diamanti, Entela ^{[2
]}

Foret, Pierre ^{[2
]}

Darque-Ceretti, Evelyne ^{[1
]}

机构：

[1] PSL Res Univ, CNRS UMR 7635, CEMEF Ctr Mat Forming, MINES ParisTech, F-06904 Sophia Antipolis, France

[2] Linde AG, D-85716 Unterschleissheim, Germany

来源：

OXIDATION OF METALS | 2014年 / 82卷 / 5-6期

关键词：

Ferritic stainless steel; Oxidation; High temperature; Short-term exposures; Water vapor; OXIDATION BEHAVIOR; ATMOSPHERES; ALLOYS; AIR; ENVIRONMENT; EVAPORATION; CHROMIUM;

D O I：

10.1007/s11085-014-9495-2

中图分类号：

TF [冶金工业];

学科分类号：

0806 ;

摘要：

This study focuses on the characterization of the oxide scales formed after different exposure times in the range of 2.5-20 min. A commercially available ferritic steel grade AISI 441 was exposed to wet argon at 1100 A degrees C with 5, 9 and 13% H2O. Raman microspectroscopy, XRD, EDS and XPS were used to fully characterize the oxide scale. For all samples exposed for over 4 min, the scale was constituted of three layers in this order: a thin top layer of spinel phases (Fe,Cr,Mn)(3)O-4 with local outgrowths; a second and main layer of Cr2O3 + (Mn,Cr)(3)O-4; and finally a bottom layer of SiO2. The uncommon presence of Fe in the top layer was also observed.

引用

页码：347 / 357

页数：11

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