Eremophilane-type sesquiterpenes from fresh rhizomes of Petasites japonicus

被引:67
作者
Tori, M [1 ]
Kawahara, M [1 ]
Sono, M [1 ]
机构
[1] Tokushima Bunri Univ, Fac Pharmaceut Sci, Tokushima 770, Japan
关键词
Petasites japonicus; Compositae; eremophilane-type sesquiterpene; epoxyeremophilanolide; eremopetasitenin; eremopetasinsulphoxide;
D O I
10.1016/S0031-9422(97)00581-5
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
Ten new eremophilane-type sesquiterpene lactones, eremopetasitenins A1, A2, B1, B2, C1, C2, C3, D1, D2, and D3, sulphoxide bearing lactone, eremopetasinsulphoxide, and two methoxyl derivatives, as well as seven previously known sesquiterpenes have been isolated from fresh rhizomes of Petasites japonicus and their structures determined by spectroscopic techniques. Epoxyeremophilanolides, eremopetasitenins Al, A2, B1, and B2, are proposed to be important biogenetic intermediates. (C) 1997 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:401 / 409
页数:9
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