Hole dynamics in noble metals

被引:57
作者
Campillo, I
Rubio, A
Pitarke, JM
Goldmann, A
Echenique, PM
机构
[1] Euskal Herriko Unibertsitatea, Zientzi Fak, Mat Kondentsatuaren Fis Saila, E-48080 Bilbao, Basque Country, Spain
[2] Univ Valladolid, Dept Fis Teor, E-47011 Valladolid, Spain
[3] Univ Gesamthsch Kassel, Fachbereich Phys, D-34132 Kassel, Germany
[4] Euskal Herriko Unibertsitatea, Kimika Fak, Mat Fis Saila, Donostia San Sebastian 20080, Basque Country, Spain
[5] UPV, EHU, CSIC, DIPC, Donostia San Sebastian, Basque Country, Spain
[6] UPV, EHU, CSIC, Ctr Mixto, Donostia San Sebastian, Basque Country, Spain
关键词
D O I
10.1103/PhysRevLett.85.3241
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
Hole dynamics;in noble metals (Cu and An) is investigated by means of first-principles many-body calculations. While holes in a free-electron gas are known to live shorter than electrons with the same excitation energy, our results indicate that d holes in noble metals exhibit longer inelastic lifetimes than excited sp electrons, in agreement with experiment. The density of states available for d-hole decay is larger than that for the decay of excited electrons; however, the small overlap between d and sp states below the Fermi level increases the d-hole lifetime. The impact of d-hole dynamics on electron-hole correlation effects is also addressed.
引用
收藏
页码:3241 / 3244
页数:4
相关论文
共 47 条
[1]   Ultrafast spin-dependent electron dynamics in fcc Co [J].
Aeschlimann, M ;
Bauer, M ;
Pawlik, S ;
Weber, W ;
Burgermeister, R ;
Oberli, D ;
Siegmann, HC .
PHYSICAL REVIEW LETTERS, 1997, 79 (25) :5158-5161
[2]   Ab initio calculation of excitonic effects in the optical spectra of semiconductors [J].
Albrecht, S ;
Reining, L ;
Del Sole, R ;
Onida, G .
PHYSICAL REVIEW LETTERS, 1998, 80 (20) :4510-4513
[3]   Measurement of monoenergetic neutrons from the (p)over-bard reaction at rest [J].
Chiba, M ;
Doi, K ;
Fujitani, T ;
Inoue, K ;
Iwahori, J ;
Kawaguti, M ;
Kobayashi, M ;
Koike, M ;
Kozuki, T ;
Kurokawa, S ;
Kusumoto, H ;
Nagano, H ;
Nagashima, Y ;
Omori, T ;
Sugimoto, S ;
Takasaki, M ;
Takeutchi, F ;
Tsuchiya, M ;
Ueda, M ;
Yamaguchi, Y ;
Yoshida, H .
PHYSICAL REVIEW D, 1997, 55 (01) :40-53
[4]   Optical absorption of insulators and the electron-hole interaction: An ab initio calculation [J].
Benedict, LX ;
Shirley, EL ;
Bohn, RB .
PHYSICAL REVIEW LETTERS, 1998, 80 (20) :4514-4517
[5]   ULTRAFAST DYNAMICS AT SEMICONDUCTOR AND METAL-SURFACES [J].
BOKOR, J .
SCIENCE, 1989, 246 (4934) :1130-1134
[6]   Phonon- versus electron-mediated desorption and oxidation of CO on Ru(0001) [J].
Bonn, M ;
Funk, S ;
Hess, C ;
Denzler, DN ;
Stampfl, C ;
Scheffler, M ;
Wolf, M ;
Ertl, G .
SCIENCE, 1999, 285 (5430) :1042-1045
[7]   First-principles calculations of hot-electron lifetimes in metals [J].
Campillo, I ;
Silkin, VM ;
Pitarke, JM ;
Chulkov, EV ;
Rubio, A ;
Echenique, PM .
PHYSICAL REVIEW B, 2000, 61 (20) :13484-13492
[8]   Ab initio calculations of the dynamical response of copper [J].
Campillo, I ;
Rubio, A ;
Pitarke, JM .
PHYSICAL REVIEW B, 1999, 59 (19) :12188-12191
[9]   Inelastic lifetimes of hot electrons in real metals [J].
Campillo, I ;
Pitarke, JM ;
Rubio, A ;
Zarate, E ;
Echenique, PM .
PHYSICAL REVIEW LETTERS, 1999, 83 (11) :2230-2233
[10]   Role of occupied d states in the relaxation of hot electrons in Au [J].
Campillo, I ;
Pitarke, JM ;
Rubio, A ;
Echenique, PM .
PHYSICAL REVIEW B, 2000, 62 (03) :1500-1503