Preparation and reactions of 2,4,6-tris(trifluoromethyl)phenylamine

被引：9
作者：
Ahlemann, JT
Roesky, HW
Noltemeyer, M
Schmidt, HG
Markovsky, LN
Shermolovich, YG
机构：
[1] Univ Gottingen, Inst Anorgan Chem, D-37077 Gottingen, Germany
[2] Natl Acad Sci Ukraine, Inst Organ Chem, UA-25660 Kyiv, Ukraine
来源：
JOURNAL OF FLUORINE CHEMISTRY | 1998年 / 87卷 / 01期
关键词：
aromatic fluorides; fluorinated amines; silicon derivatives;
D O I：
10.1016/S0022-1139(97)00097-3
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Starting from RfH (1) [R-f=1,3,5-tris(trifluoromethyl)phenyl] RfNH2 (6) is obtained in a four-step synthesis. The amine 6 reacts with chlorotrimethylsilane in the presence of DBU (1,8-diazabicyclo(5,4,0)undec-7-ene) forming the monosilylated and the bissilylated amines 7 and 8. The potassium salt of 7 reacts with SiCl4 yielding RfN(SiCl3), (10). The single crystal X-ray structure of 10 is reported. (C) 1998 Elsevier Science S.A.
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页码：87 / 90
页数：4
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