Suppression of electron spin-echo envelope modulation peaks in double quantum coherence electron spin resonance

被引：34
作者：
Bonora, M [1 ]
Becker, J [1 ]
Saxena, S [1 ]
机构：
[1] Univ Pittsburgh, Dept Chem, Pittsburgh, PA 15260 USA
来源：
JOURNAL OF MAGNETIC RESONANCE | 2004年 / 170卷 / 02期
基金：
美国国家科学基金会;
关键词：
double quantum ESR; dipolar interactions; FT-ESR; distance measurements; spin-labeling;
D O I：
10.1016/j.jmr.2004.07.006
中图分类号：
Q5 [生物化学];
学科分类号：
071010 ; 081704 ;
摘要：
We show the use of the observer blind spots effect for the elimination of electron spin-echo envelope modulation (ESEEM) peaks in double quantum coherence (DQC) electron spin resonance (ESR). The suppression of ESEEM facilitates the routine and unambiguous extraction of distances from DQC-ESR spectra. This is also the first demonstration of this challenging methodology on commercial instrumentations. (C) 2004 Elsevier Inc. All rights reserved.
引用
收藏
页码：278 / 283
页数：6
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