Comment on "Effect of BO4 and FeO4 Structural Units on Conduction Mechanism of Iron Borosilicate Glasses"

被引:0
|
作者
Nayak, Pranaba K. [1 ]
机构
[1] Tata Inst Fundamental Res, Dept High Energy Phys, Homi Bhabha Rd, Mumbai 400005, Maharashtra, India
关键词
Energy dispersive X-ray analysis; X-ray; Glass; SEM-EDAX; FE-57; MOSSBAUER;
D O I
10.1007/s12633-022-02003-z
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Recently, El-Damrawi et al. (Silicon 13:4025-4031, 2021) reported the Effect of BO4 and FeO4 Structural Units on Conduction Mechanism of Iron Borosilicate glasses using several complementary techniques, where the study involving energy dispersive X-ray analysis (EDAX) is erroneous and scientifically unacceptable. They inferred from EDAX that the Fe L X-ray lines arising from Fe3+ situated at the octahedral site and K X-ray lines are due to Fe2+ situated at tetrahedral sites, which is incorrect and not based on factual experimental observation. In its present form, Figs. 1, 2, 3, 4 (original Figs. 7-10 in the main paper (El-Damrawi et al. in Silicon 13:4025-4031, 2021)) violets the basic understanding of the EDAX technique, portraying the feature of the technique other than the actual possible scientific outcome.
引用
收藏
页码:12931 / 12934
页数:4
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