Chemoselective flow hydrogenation of α,β - Unsaturated aldehyde with nano-nickel

被引：18

作者：

Gizinski, Damian ^{[1
]}

Goszewska, Ilona ^{[1
]}

Zielinski, Maciej ^{[1
]}

Lisovytskiy, Dmytro ^{[1
]}

Nikiforov, Kostiantyn ^{[1
]}

Masternak, Joanna ^{[2
]}

Zienkiewicz-Machnik, Malgorzata ^{[1
]}

Srebowata, Anna ^{[1
]}

Sa, Jacinto ^{[1
,3
]}

机构：

[1] Polish Acad Sci, Inst Phys Chem, Kasprzaka 44-52, PL-01224 Warsaw, Poland

[2] Jan Kochanowski Univ, Inst Chem, Swietokrzyska 15G, PL-25406 Kielce, Poland

[3] Uppsala Univ, Dept Chem, Angstrom Lab, S-75120 Uppsala, Sweden

来源：

CATALYSIS COMMUNICATIONS | 2017年 / 98卷

关键词：

Hydrogenation in flow; Nano-nickel catalyst; Resin supported catalyst; Selective hydrogenation of alpha; beta-unsaturated; aldehydes; RAY PHOTOELECTRON-SPECTROSCOPY; LIQUID-PHASE HYDROGENATION; SELECTIVE HYDROGENATION; FACILE SYNTHESIS; CINNAMALDEHYDE; NANOPARTICLES; CATALYST; CU; PERFORMANCE; XPS;

D O I：

10.1016/j.catcom.2017.04.048

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Herein, it is presented a novel catalytic system for the continuous flow chemoselective hydrogenation of a,alpha,beta- unsaturated aldehydes used in the production of high value cosmetics and pharmaceuticals precursors. The reaction was catalyzed by nano nickel particles grafted on polymeric support, synthesized via a simple, adaptable and green methodology. The system was highly active and very selective to C=C bond saturation.

引用

页码：17 / 21

页数：5

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