Syntheses and structures of two anion-templated dinuclear cadmium complexes with diamino-binaphthyl Schiff bases as ligands

被引：36

作者：

Shi, Q

Xu, LJ ^{[1
]}

Ji, JX

Li, YM

Wang, RH

Zhou, ZY

Cao, R

Hong, MC

Chan, ASC

机构：

[1] Hong Kong Polytech Univ, Dept Appl Biol & Chem Technol, Open Lab Chirotechnol, Kowloon, Hong Kong, Peoples R China

[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 325000, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2004年 / 7卷 / 12期

关键词：

anion-templated; cadmium(II); Schiff base; binaphthyl;

D O I：

10.1016/j.inoche.2004.09.017

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two cadmium(II) complexes, [(CdLCl2)-Cl-1](2) . 2CH(3)OH and [CdL2(SCN)(2)](2) . CH3OH (1 and 2), were prepared by mixing 2,2-diamino-1,1'-binaphthalene and 2-pyridyl-carboxaldehyde in the presence of two different cadmium(II) salts. The Schiff base ligand appeared in complex 1 has only one imine group, while in complex 2 both amino groups were reacted to form two imine groups. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：1254 / 1257

页数：4

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