Free jet rotational spectrum of the most stable conformer of 1-(2-fluorophenyl)-1-ethanol

被引：3

作者：

Tang, Shouyuan ^{[2
]}

Caminati, Walther ^{[1
]}

机构：

[1] Univ Bologna, Dipartimento Chim G Ciamician, I-40126 Bologna, Italy

[2] Chongqing Univ, Coll Urban Construct & Environm Engn, Chongqing 400044, Peoples R China

来源：

JOURNAL OF MOLECULAR SPECTROSCOPY | 2010年 / 260卷 / 02期

关键词：

Rotational spectroscopy; Conformational equilibria; Jet spectroscopy; Chiral molecules; METHYL LACTATE CLUSTERS; MICROWAVE; DISCRIMINATION; SPECTROSCOPY; RECOGNITION; COMPLEXES; ALCOHOLS; DIMERS;

D O I：

10.1016/j.jms.2010.01.007

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

The most stable conformer of chiral 1-(2-fluorophenyl)-1-ethanol is stabilized by a O-H center dot center dot center dot pi interaction and it is at least 1 kcal/mol more stable than the remaining conformers. This is the result of a free jet millimeter-wave absorption spectroscopy investigation of the rotational spectra of the most abundant and O-d isotopic species. (C) 2010 Elsevier Inc. All rights reserved.

引用

页码：120 / 123

页数：4

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