High performance binder-free quaternary composite CuO/Cu/TiO2NT/Ti anode for lithium ion battery

被引：24
|
作者：
Meng, Ruijin [1 ]
Hou, Hongying [1 ]
Liu, Xianxi [2 ]
Yan, Cuixia [1 ]
Duan, Jixiang [1 ]
Liu, Song [1 ]
机构：
[1] Kunming Univ Sci & Technol, Fac Mat Sci & Engn, Kunming 650093, Peoples R China
[2] Kunming Univ Sci & Technol, Fac Mech & Elect Engn, Kunming 650093, Peoples R China
来源：
CERAMICS INTERNATIONAL | 2016年 / 42卷 / 05期
基金：
中国国家自然科学基金;
关键词：
Binder-free quaternary composite; CuO/Cu/TiO2NT/Ti; Anode active material; Lithium ion battery; TIO2; NANOTUBE; CUO; FABRICATION; SUBSTRATE; ELECTRODE; NANOSHEETS; REDUCTION; ARRAYS; CU2O;
D O I：
10.1016/j.ceramint.2015.12.160
中图分类号：
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
High performance binder-free quaternary composite CuO/Cu/TiO2 nanotube/Ti (CuO/Cu/TiO2NT/Ti) electrode for lithium ion battery was designed and synthesized via anodization, electrodeposition and thermal oxidation at 450 degrees C in the air. The as-prepared binder-free quaternary composite CuO/Cu/TiO2NT/Ti electrode was studied in terms of XRD, XPS, SEM, EDX, galvanostatic charge/discharge, cycle stability, cyclic voltammetry (CV) and AC impedance. As expected, the binder-free quaternary composite CuO/Cu/TiO2NT/Ti electrode displayed much higher discharge capacity, cycle stability, Li+ diffusion coefficient than bare TiO2NT/Ti electrode. High Li-storage activity of CuO, high conductivity of Cu and the synergy effect among various components should be responsible for improved electrochemical performances. Additionally, binder free combination of the various components may also contribute into the modifications due to the exclusion of negative effect of polymer binder. (C) 2016 Elsevier Ltd and Techna Group S.r.l. All rights reserved.
引用
收藏
页码：6039 / 6045
页数：7
相关论文
共 50 条
  • [41] Sol-gel nanoglues for an organic binder-free TiO2 nanofiber anode for lithium ion batteries
    Choi, Junghyun
    Lee, Sangkyu
    Ha, Jaehwan
    Song, Taeseup
    Paik, Ungyu
    NANOSCALE, 2013, 5 (08) : 3230 - 3234
  • [42] A facile strategy to construct binder-free flexible carbonate composite anode at low temperature with high performances for lithium-ion batteries
    Shi, Shaojun
    Zhang, Ming
    Deng, Tingting
    Wang, Ting
    Yang, Gang
    ELECTROCHIMICA ACTA, 2017, 246 : 1004 - 1015
  • [43] Nitrogen Rich Carbon Coated TiO2 Nanoparticles as Anode for High Performance Lithium-ion Battery
    Senthil, Chenrayan
    Kesavan, Thangaian
    Bhaumik, Asim
    Yoshio, Masaki
    Sasidharan, Manickam
    ELECTROCHIMICA ACTA, 2017, 255 : 417 - 427
  • [44] One-step solid-phase synthesis of binder-free molybdenum disulfide/carbon fibers paper anode for high-performance lithium-ion batteries
    He, Wenyuan
    Zheng, Xuejun
    Peng, Jinfeng
    Zhang, Qiang
    Pei, Dazhao
    Yan, Xinyang
    JOURNAL OF ALLOYS AND COMPOUNDS, 2018, 768 : 33 - 41
  • [45] Binder-Free LiCoO2/Carbon Nanotube Cathodes for High-Performance Lithium Ion Batteries
    Luo, Shu
    Wang, Ke
    Wang, Jiaping
    Jiang, Kaili
    Li, Qunqing
    Fan, Shoushan
    ADVANCED MATERIALS, 2012, 24 (17) : 2294 - 2298
  • [46] ZnO Nanomembrane/Expanded Graphite Composite Synthesized by Atomic Layer Deposition as Binder-Free Anode for Lithium Ion Batteries
    Li, Yalan
    Zhao, Yuting
    Huang, Gaoshan
    Xu, Borui
    Wang, Bing
    Pan, Ruobing
    Men, Chuanling
    Mei, Yongfeng
    ACS APPLIED MATERIALS & INTERFACES, 2017, 9 (44) : 38522 - 38529
  • [47] Synthesis of graphene quantum dots-coated hierarchical CuO microspheres composite for use as binder-free anode for lithium-ion batteries
    Kim, Jongmin
    Jang, Wooree
    Kim, Ji Hoon
    Yang, Cheol-Min
    COMPOSITES PART B-ENGINEERING, 2021, 222
  • [48] Nitrogen dual-doped porous carbon fiber: A binder-free and high-performance flexible anode for lithium ion batteries
    Zhang, Qian
    Zhou, Kang
    Lei, Jiehong
    Hu, Wencheng
    APPLIED SURFACE SCIENCE, 2019, 467 : 992 - 999
  • [49] High capacity performance of NiCo2O4 nanostructures as a binder-free anode material for lithium-ion batteries
    Kakarla, Ashok Kumar
    Narsimulu, D.
    Yu, Jae Su
    INTERNATIONAL JOURNAL OF ENERGY RESEARCH, 2021, 45 (09) : 13355 - 13364
  • [50] Preparation of SnO2/TiO2/C composite fibres and their use as binder-free anodes for lithium-ion batteries
    Gonzalez, Gabriel
    Sanchez, David
    Ramirez, Daniel
    Myers, Jason C.
    Lodge, Timothy P.
    Parsons, Jason
    Alcoutlabi, Mataz
    BULLETIN OF MATERIALS SCIENCE, 2023, 46 (02)
12345