Infrared spectra of antimony and bismuth hydrides in solid matrixes

被引：24

作者：

Wang, XF ^{[1
]}

Souter, PF ^{[1
]}

Andrews, L ^{[1
]}

机构：

[1] Univ Virginia, Dept Chem, Charlottesville, VA 22904 USA

来源：

JOURNAL OF PHYSICAL CHEMISTRY A | 2003年 / 107卷 / 21期

关键词：

AB-INITIO PSEUDOPOTENTIALS; LOW-LYING STATES; CONFIGURATION-INTERACTION; SPECTROSCOPIC PROPERTIES; HIGH-RESOLUTION; MOLECULES; ATOMS; BIH; ACCURATE; HYDROGEN;

D O I：

10.1021/jp034379y

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Laser-ablated Sb and Bi atoms react with hydrogen during condensation in excess hydrogen, neon, and argon to form the SbH and BiH diatomic molecules. In addition the new Group 15 MH2 dihydride radicals and the MH3 trihydrides are observed for Sb and Bi metals. Although BiH3 is of limited stability in the gas phase, BiH3 is formed by further H atom reactions with BiH2 in solid hydrogen and neon. No evidence is found for the thermochemically unstable BiH5 molecule.

引用

页码：4244 / 4249

页数：6

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