Infrared spectra of antimony and bismuth hydrides in solid matrixes

被引：24

作者：

Wang, XF ^{[1
]}

Souter, PF ^{[1
]}

Andrews, L ^{[1
]}

机构：

[1] Univ Virginia, Dept Chem, Charlottesville, VA 22904 USA

来源：

JOURNAL OF PHYSICAL CHEMISTRY A | 2003年 / 107卷 / 21期

关键词：

AB-INITIO PSEUDOPOTENTIALS; LOW-LYING STATES; CONFIGURATION-INTERACTION; SPECTROSCOPIC PROPERTIES; HIGH-RESOLUTION; MOLECULES; ATOMS; BIH; ACCURATE; HYDROGEN;

D O I：

10.1021/jp034379y

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Laser-ablated Sb and Bi atoms react with hydrogen during condensation in excess hydrogen, neon, and argon to form the SbH and BiH diatomic molecules. In addition the new Group 15 MH2 dihydride radicals and the MH3 trihydrides are observed for Sb and Bi metals. Although BiH3 is of limited stability in the gas phase, BiH3 is formed by further H atom reactions with BiH2 in solid hydrogen and neon. No evidence is found for the thermochemically unstable BiH5 molecule.

引用

页码：4244 / 4249

页数：6

共 50 条

[21] INFRARED REFLECTION SPECTRA OF BISMUTH TITANATE
KNYAZEV, AS
ZAKHAROV, VP
POPLAVKO, YM
FIZIKA TVERDOGO TELA, 1976, 18 (11): : 3538 - 3539
[22] The nature of the solid phase in the system antimony-bismuth
Ehret, WF
Abramson, MB
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1934, 56 : 385 - 388
[23] INTERFACIAL PHENOMENA ON DISSOLUTION OF SOLID ANTIMONY INTO MOLTEN BISMUTH
SHOJI, Y
UCHIDA, S
TRANSACTIONS OF THE JAPAN INSTITUTE OF METALS, 1981, 22 (09): : 653 - 658
[24] SOLID-SOLUTIONS BASED ON BISMUTH AND ANTIMONY CHALCOGENIDES
ANUKHIN, AI
ZHMURKO, AI
KLYUCHNIKOV, VP
INORGANIC MATERIALS, 1983, 19 (08) : 1151 - 1153
[25] INFRARED SPECTRA OF DIAZONIUM SALTS OF PENTAVALENT ANTIMONY
KAZITSYNA, LA
KUZNETSOV, AV
REUTOV, OA
JOURNAL OF GENERAL CHEMISTRY USSR, 1963, 33 (07): : 2186 - &
[26] MAGNETIC PROPERTIES OF METALS - SOLID SOLUTIONS OF ANTIMONY IN BISMUTH
VERKIN, BI
KUZMICHE.LB
SVECHKAR.IV
JETP LETTERS-USSR, 1967, 6 (07): : 225 - &
[27] Researches on the spectra of the tin, lead, antimony, and bismuth in the magnetic field
van der Harst, PA
PROCEEDINGS OF THE KONINKLIJKE AKADEMIE VAN WETENSCHAPPEN TE AMSTERDAM, 1920, 22 (1/5): : 300 - 312
[28] SOLID-STATE CHEMISTRY IN ANTIMONY PENTAFLUORIDE MATRICES - INFRARED-SPECTRA OF REACTIVE INTERMEDIATES
VANCIK, H
SUNKO, DE
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (10) : 3742 - 3744
[29] SOLVENT EFFECTS ON INFRARED SPECTRA OF INORGANIC COMPLEX HYDRIDES
ADAMS, DM
PROCEEDINGS OF THE CHEMICAL SOCIETY OF LONDON, 1961, (NOV): : 431 - &
[30] INFRARED AND RAMAN-SPECTRA OF NONSTOICHIOMETRIC CERIUM HYDRIDES
FUJIMORI, A
ISHII, M
TSUDA, N
PHYSICA STATUS SOLIDI B-BASIC RESEARCH, 1980, 99 (02): : 673 - 681

← 1 2 3 4 5 →