Potassium-Based Dual Ion Battery with Dual-Graphite Electrode

被引:180
作者
Fan, Ling [1 ]
Liu, Qian [1 ]
Chen, Suhua [1 ]
Lin, Kairui [2 ]
Xu, Zhi [3 ]
Lu, Bingan [1 ,3 ]
机构
[1] Hunan Univ, Sch Phys & Elect, State Key Lab Adv Design & Mfg Vehicle Body, Changsha 410082, Hunan, Peoples R China
[2] Quanzhou Number Fifth High Sch ChengDong, Quanzhou 362000, Peoples R China
[3] Fujian Strait Res Inst Ind Graphene Technol, Jinjiang 362200, Peoples R China
基金
中国国家自然科学基金;
关键词
HIGH-CAPACITY; BIS(TRIFLUOROMETHANESULFONYL)IMIDE ANIONS; ELECTROCHEMICAL INTERCALATION; ENERGY; GRAPHENE; CATHODE; LITHIUM; SULFUR; ANODE;
D O I
10.1002/smll.201701011
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A potassium ion battery has potential applications for large scale electric energy storage systems due to the abundance and low cost of potassium resources. Dual graphite batteries, with graphite as both anode and cathode, eliminate the use of transition metal compounds and greatly lower the overall cost. Herein, combining the merits of the potassium ion battery and dual graphite battery, a potassium-based dual ion battery with dual-graphite electrode is developed. It delivers a reversible capacity of 62 mA h g(-1) and medium discharge voltage of approximate to 3.96 V. The intercalation/deintercalation mechanism of K+ and PF6- into/from graphite is proposed and discussed in detail, with various characterizations to support.
引用
收藏
页数:7
相关论文
共 39 条
[1]   A Dual-Ion Battery Cathode via Oxidative Insertion of Anions in a Metal-Organic Framework [J].
Aubrey, Michael L. ;
Long, Jeffrey R. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2015, 137 (42) :13594-13602
[2]   Organic electrode for non-aqueous potassium-ion batteries [J].
Chen, Yanan ;
Luo, Wei ;
Carter, Marcus ;
Zhou, Lihui ;
Dai, Jiaqi ;
Fu, Kun ;
Lacey, Steven ;
Li, Tian ;
Wan, Jiayu ;
Han, Xiaogang ;
Bao, Yanping ;
Hu, Liangbing .
NANO ENERGY, 2015, 18 :205-211
[3]   Structurally stable Mg-doped P2-Na2/3Mn1-yMgyO2 sodium-ion battery cathodes with high rate performance: insights from electrochemical, NMR and diffraction studies [J].
Clement, Raphaele J. ;
Billaud, Juliette ;
Armstrong, A. Robert ;
Singh, Gurpreet ;
Rojo, Teofilo ;
Bruce, Peter G. ;
Grey, Clare P. .
ENERGY & ENVIRONMENTAL SCIENCE, 2016, 9 (10) :3240-3251
[4]   Energy and capacity projections for practical dual-graphite cells [J].
Dahn, JR ;
Seel, JA .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2000, 147 (03) :899-901
[5]   Hierarchical zigzag Na1.25V3O8 nanowires with topotactically encoded superior performance for sodium-ion battery cathodes [J].
Dong, Yifan ;
Li, Shuo ;
Zhao, Kangning ;
Han, Chunhua ;
Chen, Wei ;
Wang, Bingliang ;
Wang, Lei ;
Xu, Boan ;
Wei, Qiulong ;
Zhang, Lei ;
Xu, Xu ;
Mai, Liqiang .
ENERGY & ENVIRONMENTAL SCIENCE, 2015, 8 (04) :1267-1275
[6]   Soft Carbon as Anode for High-Performance Sodium-Based Dual Ion Full Battery [J].
Fan, Ling ;
Liu, Qian ;
Chen, Suhua ;
Xu, Zhi ;
Lu, Bingan .
ADVANCED ENERGY MATERIALS, 2017, 7 (14)
[7]   Covalent sulfur for advanced room temperature sodium-sulfur batteries [J].
Fan, Ling ;
Ma, Ruifang ;
Yang, Yuhua ;
Chen, Suhua ;
Lu, Bingan .
NANO ENERGY, 2016, 28 :304-310
[8]   Reactive Oxygen-Doped 3D Interdigital Carbonaceous Materials for Li and Na Ion Batteries [J].
Fan, Ling ;
Lu, Bingan .
SMALL, 2016, 12 (20) :2783-2791
[9]   An Iodine Quantum Dots Based Rechargeable Sodium-Iodine Battery [J].
Gong, Decai ;
Wang, Bin ;
Zhu, Jingyi ;
Podila, Ramakrishna ;
Rao, Apparao M. ;
Yu, Xinzhi ;
Xu, Zhi ;
Lu, Bingan .
ADVANCED ENERGY MATERIALS, 2017, 7 (03)
[10]   Evolution of Strategies for Modern Rechargeable Batteries [J].
Goodenough, John B. .
ACCOUNTS OF CHEMICAL RESEARCH, 2013, 46 (05) :1053-1061