Greener Biogenic Approach for the Synthesis of Palladium Nanoparticles Using Papaya Peel: An Eco-Friendly Catalyst for C-C Coupling Reaction

被引:59
作者
Dewan, Anindita [1 ]
Sarmah, Manashi [1 ]
Thakur, Ashim J. [1 ]
Bharali, Pankaj [1 ]
Bora, Utpal [1 ]
机构
[1] Tezpur Univ, Dept Chem Sci, Tezpur 784028, Assam, India
来源
ACS OMEGA | 2018年 / 3卷 / 05期
关键词
HIGHLY EFFICIENT; SUPPORTED PALLADIUM; ARYL IODIDES; IN-SITU; SUZUKI; SONOGASHIRA; WATER; HECK; DERIVATIVES; DEGRADATION;
D O I
10.1021/acsomega.8b00039
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The development of a green and sustainable synthetic methodology still remains a challenge across the globe. Encouraging the prevailing challenge, herein, we have synthesized Pd nanoparticles (Pd NPs) in a green and environmentally viable route, using the extract of waste papaya peel without the assistance of any reducing agents, high-temperature calcination, and reduction procedures. The biomolecules present in the waste papaya peel extract reduced Pd(II) to nanosize Pd(0) in a one-pot green and sustainable process. As a catalyst, the new Pd NPs offer a simple and efficient methodology in direct Suzuki-Miyaura and Sonogashira coupling with excellent yields under mild reaction conditions.
引用
收藏
页码:5327 / 5335
页数:9
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