Synthesis of a Fullerene End-capped Poly (ε-caprolactone) by Fullerene Derivative Initiator

被引:0
作者
Peng Qi-Yun [1 ]
Kang Feng [1 ]
Li Juan [1 ]
Yang Xin-Lin [1 ]
机构
[1] Beijing Inst Technol, Sch Life Sci & Technol, Beijing 100081, Peoples R China
来源
CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE | 2010年 / 31卷 / 01期
关键词
Fullerene end-capped poly (epsilon-caprolactone); epsilon-Caprolactone; Ming-opening polymerization; POLY(ETHYLENE OXIDE); MECHANICAL-BEHAVIOR; C-60;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Using N-substituted 3 4-fullero pyrrolidine with an active hydroxyl group as an initiator, polymerization of epsilon-caprolactone was performed via ring-opening polymerization. The product was characterized by H-1 NMR, C-13 NMR and MALDT-TOF MS and its thermal properties were determined by TG and DSC. The results show that a fullerene end-capped poly(epsilon-caprolactone) is achieved, and the product is more thermally tolerative than poly(epsilon-caprolactone)
引用
收藏
页码:177 / 180
页数:4
相关论文
共 28 条
[1]  
Anton W. J., 1996, BIOORGAN MED CHEM, V4, P767
[2]   Asymmetric and mikto-arm stars with a C60 core by grafting of macro-radicals or anionic polymer chains [J].
Audouin, F ;
Renouard, T ;
Schmaltz, B ;
Nuffer, R ;
Mathis, C .
POLYMER, 2005, 46 (19) :8519-8527
[3]   Fullerene derivatives: an attractive tool for biological applications [J].
Bosi, S ;
Da Ros, T ;
Spalluto, G ;
Prato, M .
EUROPEAN JOURNAL OF MEDICINAL CHEMISTRY, 2003, 38 (11-12) :913-923
[4]   Preparation of C60-functionalized magnetic silica microspheres for the enrichment of low-concentration peptides and proteins for MALDI-TOF MS analysis [J].
Chen, Hemei ;
Qi, Dawei ;
Deng, Chunhui ;
Yang, Penyuan ;
Zhang, Xiangmin .
PROTEOMICS, 2009, 9 (02) :380-387
[5]  
CHEN JH, 1993, ACTA POLYM SIN, P356
[6]  
CHIANG LY, 1994, CHEM COMMUN, V23, P2675
[7]  
Dai LM, 2001, ADV MATER, V13, P899, DOI 10.1002/1521-4095(200107)13:12/13<899::AID-ADMA899>3.0.CO
[8]  
2-G
[9]   Fullerene polymers:: Synthesis and properties [J].
Giacalone, Francesco ;
Martin, Nazario .
CHEMICAL REVIEWS, 2006, 106 (12) :5136-5190
[10]   Fullerene-based organic-inorganic nanocomposites and their applications [J].
Innocenzi, P ;
Brusatin, G .
CHEMISTRY OF MATERIALS, 2001, 13 (10) :3126-3139