Photodoping and Enhanced Visible Light Absorption in Single-Walled Carbon Nanotubes Functionalized with a Wide Band Gap Oligomer

被引:22
作者
Bunes, Benjamin R. [1 ,2 ]
Xu, Miao [1 ,2 ]
Zhang, Yaqiong [1 ,2 ]
Gross, Dustin E. [3 ]
Saha, Avishek [4 ,5 ]
Jacobs, Daniel L. [1 ,2 ]
Yang, Xiaomei [1 ,2 ]
Moore, Jeffrey S. [6 ,7 ]
Zang, Ling [1 ,2 ]
机构
[1] Univ Utah, Nano Inst Utah, Salt Lake City, UT 84112 USA
[2] Univ Utah, Dept Mat Sci & Engn, Salt Lake City, UT 84112 USA
[3] Univ Illinois, Dept Chem, Urbana, IL 61801 USA
[4] Rice Univ, Smalley Inst Nanoscale Sci & Technol, Houston, TX 77005 USA
[5] Rice Univ, Dept Chem, Houston, TX 77005 USA
[6] Univ Illinois, Dept Chem, Urbana, IL 61801 USA
[7] Univ Illinois, Dept Mat Sci & Engn, Urbana, IL 61801 USA
关键词
ELECTRONIC-PROPERTIES; CHARGE-TRANSFER; ASSISTED DISPERSION; SOLAR-CELLS; POLYMER; PHOTOVOLTAICS; TRANSISTORS; HETEROJUNCTION; DEVICES;
D O I
10.1002/adma.201404112
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Graph Presented).Carbon nanotubes feature excellent electronic properties but narrow absorption bands limit their utility in certain optoelectronic devices, including photovoltaic cells. Here, the addition of a wide-bandgap oligomer enhances light absorption in the visible spectrum. Furthermore, the oligomer interacts with the carbon nanotube through a peculiar charge transfer, which provides insight into Type II heterojunctions. © 2014 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:162 / 168
页数:7
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