Selective dimerization of cyclohexene over a Re2O7-B2O3/Al2O3 catalyst under mild conditions

被引：1

作者：

Greish, Alexander A. ^{[1
]}

Barkova, Alexandra P. ^{[1
]}

Finashina, Elena D. ^{[1
]}

Salmi, Tapio O. ^{[2
]}

Kustov, Leonid M. ^{[1
,3
,4
]}

机构：

[1] ND Zelinskii Inst Organ Chem, Leninsky Prosp 47, Moscow 119991, Russia

[2] Abo Akad Univ, Biskopsgatan 8, Turku, Finland

[3] Moscow MV Lomonosov State Univ, Dept Chem, Leninskie Gory 1,Bldg 3, Moscow 119991, Russia

[4] Natl Univ Sci & Technol MISiS, Leninsky Prosp 4, Moscow 119991, Russia

来源：

MOLECULAR CATALYSIS | 2021年 / 502卷

基金：

俄罗斯科学基金会;

关键词：

Bifunctional catalysis; Cyclohexene; 1-cyclohexenylcyclohexane; Dimerization; Rhenium; Boron; OLEFIN METATHESIS;

D O I：

10.1016/j.mcat.2021.111398

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A Re2O7-B2O3/Al2O3 catalyst was demonstrated to reveal significant activity in cyclohexene dimerization into 1cyclohexenylcyclohexane with a total yield of 95 % and a selectivity close to 100 % in the batch mode at 75-80?C and atmospheric pressure. <comment>Superscript/Subscript Available</comment

引用

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