Solvothermal controllable synthesis of polymorphic manganese oxalate anode for lithium-ion batteries

Manganese oxalate is a low-cost and high-capacity anode for lithium-ion batteries (LIBs). However, its performance is limited by the low conductivity and the volume change during charge/discharge processes. Herein, polymorphic manganese oxalates were controllably synthesized by a solvothermal process. Monoclinic alpha-MnC2O4 center dot 2H(2)O with space group C2/c can be prepared with the reactant concentration below 0.2 mol center dot L-1, while orthonormal MnC2O4 center dot 3H(2)O with space group Pcaa can be prepared with the reactant concentration above 0.2 mol center dot L-1. After removing crystal water, MnC2O4 center dot 2H(2)O and MnC2O4 center dot 3H(2)O are transformed into orthonormal MnC2O4. When the reactant concentration increases from 0.1 to 0.3 mol center dot L-1, manganese oxalate changes from rods to cubes, and its specific surface area and pore volume first increase and then decrease. Mesoporous MnC2O4 rod prepared at 0.2 mol center dot L-1 has a larger specific surface area and pore volume. This rod-like sample can maintain 920 and 790 mAh center dot g(-1) after 300 cycles 2 and 5 A center dot g(-1), respectively, exhibiting higher specific capacity, better cycle stability, and better rate performance. Therefore, the prepared mesoporous MnC2O4 rod can potentially apply in high-energy-density LIBs.