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A Water-Stable 3D Luminescent Metal-Organic Framework Based on Heterometallic [Eu6IIIZnII] Clusters Showing Highly Sensitive, Selective, and Reversible Detection of Ronidazole
被引:140
作者:
Zhang, Qingfu
[1
]
Lei, Mingyuan
[1
]
Yan, Hui
[1
]
Wang, Jinyun
[2
]
Shi, Yang
[1
]
机构:
[1] Liaocheng Univ, Coll Chem & Chem Engn, Liaocheng 252059, Peoples R China
[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, Fuzhou 350002, Peoples R China
关键词:
NITROAROMATIC EXPLOSIVES;
COORDINATION POLYMERS;
AQUEOUS-MEDIUM;
PICRIC ACID;
PHOTOLUMINESCENCE;
CATIONS;
SENSOR;
SERIES;
FILMS;
IONS;
D O I:
10.1021/acs.inorgchem.7b01156
中图分类号:
O61 [无机化学];
学科分类号:
070301 ;
081704 ;
摘要:
A water-stable 3D luminescent metal organic framework (MOP), [Eu6Zn(mu 3-OH)(8)(NDC)(6)(H2O)(6)] (1), constructed from heterometallic [(Eu6ZnII)-Zn-III] clusters and electron-rich pi-conjugated 1,4-naphthalenedicarboxylic acid (H2NDC) ligands exhibits highly sensitive, selective, and reversible detection of ronidazole, which represents the first example of luminescent MOFs based on Ln-TM heterometallic clusters for the detection of antibiotics in aqueous solution.
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页码:7610 / 7614
页数:5
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