Structural incorporation of iron into Ge-imogolite nanotubes: a promising step for innovative nanomaterials

被引:29
作者
Avellan, A. [1 ,2 ]
Levard, C. [1 ,2 ]
Kumar, N. [1 ,2 ]
Rose, J. [1 ,2 ]
Olivi, L. [3 ]
Thill, A. [4 ]
Chaurand, P. [1 ,2 ]
Borschneck, D. [1 ,2 ]
Masion, A. [1 ,2 ]
机构
[1] Aix Marseille Univ, CNRS, CEREGE, IRD,UM34,UMR 7330, F-13545 Aix En Provence, France
[2] Duke Univ, CNRS, iCEINT Int Ctr Environm Implicat NanoTechol, F-13545 Aix En Provence, France
[3] ELETTRA, Synchrotron Light Source, I-34012 Trieste, Italy
[4] CEA Saclay, IRAMIS, Lab Interdisciplinaire Org Nanometr & Supramol, F-91191 Gif Sur Yvette, France
关键词
ADSORPTION; ALUMINOSILICATE; HYDROLYSIS; SPECIATION; CATALYST; MODELS;
D O I
10.1039/c4ra08840a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Novel iron-doped aluminogermanate nanotubes were obtained using a single step, aqueous phase synthesis protocol. These nanotubes are isostructural with imogolite, a natural occurring nanofiber, but are obtained by-product free in substantially larger quantities with aluminum substitution levels around 1%. Increasing the Fe concentrations led to higher substitution levels but also to the co-precipitation of Fe (oxy)hydroxides.
引用
收藏
页码:49827 / 49830
页数:4
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