Copper diimine complexes:: the synthesis and crystal structures of [Cu(C10H14N2)2(MeOH)][BF4], [Cu(C10H20N2)2]Br, [{(C10H14N2)CuBr(μ-OMe)}2(MeOH)] and [{(C10H20N2)CuBr(μ-OMe)}2]

被引：31

作者：

Haddleton, DM ^{[1
]}

Clark, AJ ^{[1
]}

Duncalf, DJ ^{[1
]}

Heming, AM ^{[1
]}

Kukulj, D ^{[1
]}

Shooter, AJ ^{[1
]}

机构：

[1] Univ Warwick, Dept Chem, Coventry CV4 7AL, W Midlands, England

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1998年 / 03期

关键词：

D O I：

10.1039/a706722d

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis and structural characterisation of related novel copper-(I) and -(II) diimine complexes have been described and their application as catalysts for atom transfer polymerisation is noted. The unexpected formation of a methoxy bridged copper(II) diimine complex [{(C10H14N2)CuBr(mu-OMe)}(2)(MeOH)] 3 from the reaction of a copper(I) diimine complex with phenol is described. Compounds 3 and [{(C10H20N2)CuBr(mu-OMe)}(2)] 4 appear to be examples of a rare class of alkoxy bridged Cu-II complexes, with very few similar examples being crystallographically characterised previously.

引用

页码：381 / 385

页数：5

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