Copper diimine complexes:: the synthesis and crystal structures of [Cu(C10H14N2)2(MeOH)][BF4], [Cu(C10H20N2)2]Br, [{(C10H14N2)CuBr(μ-OMe)}2(MeOH)] and [{(C10H20N2)CuBr(μ-OMe)}2]

被引：31

作者：

Haddleton, DM ^{[1
]}

Clark, AJ ^{[1
]}

Duncalf, DJ ^{[1
]}

Heming, AM ^{[1
]}

Kukulj, D ^{[1
]}

Shooter, AJ ^{[1
]}

机构：

[1] Univ Warwick, Dept Chem, Coventry CV4 7AL, W Midlands, England

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1998年 / 03期

关键词：

D O I：

10.1039/a706722d

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis and structural characterisation of related novel copper-(I) and -(II) diimine complexes have been described and their application as catalysts for atom transfer polymerisation is noted. The unexpected formation of a methoxy bridged copper(II) diimine complex [{(C10H14N2)CuBr(mu-OMe)}(2)(MeOH)] 3 from the reaction of a copper(I) diimine complex with phenol is described. Compounds 3 and [{(C10H20N2)CuBr(mu-OMe)}(2)] 4 appear to be examples of a rare class of alkoxy bridged Cu-II complexes, with very few similar examples being crystallographically characterised previously.

引用

页码：381 / 385

页数：5

共 31 条

[1] Application of indane-derived C-2-symmetric bis(oxazolines) in two-point binding asymmetric Diels-Alder reactions [J].

Davies, IW ;

Senanayake, CH ;

Larsen, RD ;

Verhoeven, TR ;

Reider, PJ .

TETRAHEDRON LETTERS, 1996, 37 (11) :1725-1726

[2] THE PREPARATION AND PROPERTIES OF OXAZIRANES [J].

EMMONS, WD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1957, 79 (21) :5739-5754

[3] BIS(OXAZOLINE) AS LIGANDS FOR SELF-ASSEMBLING CHIRAL COORDINATION POLYMERS - STRUCTURE OF A COPPER(I) CATALYST FOR THE ENANTIOSELECTIVE CYCLOPROPANATION OF OLEFINS [J].

EVANS, DA ;

WOERPEL, KA ;

SCOTT, MJ .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1992, 31 (04) :430-432

[4] THE CRYSTAL-STRUCTURE AND ELECTRONIC-PROPERTIES OF BIS(2,2'-BIPYRIDYL)COPPER(II) BIS(HEXAFLUOROPHOSPHATE) [J].

FOLEY, J ;

TYAGI, S ;

HATHAWAY, BJ .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1984, (01) :1-5

[5]

Giese B., 1988, RADICALS ORGANIC SYN

[6] Controlled/''living'' radical polymerization of methyl methacrylate by atom transfer radical polymerization [J].

Grimaud, T ;

Matyjaszewski, K .

MACROMOLECULES, 1997, 30 (07) :2216-2218

[7] Atom transfer radical polymerization of methyl methacrylate initiated by alkyl bromide and 2-pyridinecarbaldehyde imine copper(I) complexes [J].

Haddleton, DM ;

Jasieczek, CB ;

Hannon, MJ ;

Shooter, AJ .

MACROMOLECULES, 1997, 30 (07) :2190-2193

[8] Atom transfer radical polymerisation (ATRP) of methyl methacrylate in the presence of radical inhibitors [J].

Haddleton, DM ;

Clark, AJ ;

Crossman, MC ;

Duncalf, DJ ;

Heming, AM ;

Morsley, SR ;

Shooter, AJ .

CHEMICAL COMMUNICATIONS, 1997, (13) :1173-1174

[9] Monohydroxy terminally functionalised poly(methyl methacrylate) from atom transfer radical polymerisation [J].

Haddleton, DM ;

Waterson, C ;

Derrick, PJ ;

Jasieczek, CB ;

Shooter, AJ .

CHEMICAL COMMUNICATIONS, 1997, (07) :683-684

[10]

HAEMAELAEINEN R, 1978, FINN CHEM LETT, P199

← 1 2 3 4 →