Syntheses, Crystal Structures, and Fluorescent Properties of Three Complexes Based on 1-((Benzotriazol-1-yl)methyl)-1-H-1,3-imdazole

被引：6

作者：

Duan, Likun ^{[1
]}

Liu, Shuangliang ^{[1
]}

Zhou, Wan ^{[1
]}

Meng, Xiangru ^{[1
]}

机构：

[1] Zhengzhou Univ, Dept Chem, Zhengzhou 450052, Peoples R China

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2010年 / 40卷 / 05期

基金：

中国国家自然科学基金;

关键词：

complex; crystal structure; fluorescent property; synthesis; COORDINATION POLYMERS; DINUCLEAR; LIGAND; LUMINESCENCE;

D O I：

10.1080/15533174.2010.486818

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Three new complexes formulated as [Zn(bmi)2Cl2] (1), [Zn(bmi)2(N3)2](2), and [Hg(bmi)Cl2]2 (3) (bmi = 1-((benzotriazol-1-yl)methyl)-1-H-1,3-imdazole) have been synthesized and characterized by elemental analysis, IR and single crystal X-ray diffraction. Complexes 1 and 2 show mononuclear structures, and complex 3 exhibits binuclear structure. In the solid state, they all possess a three-dimensional network formed by hydrogen bonds and - interactions. Their fluorescent properties have also been determined.

引用

页码：319 / 327

页数：9

共 15 条

[1]

[Anonymous], 1997, SHELXTL 97 PROGRAM R

[2] Mononuclear to polynuclear transition induced by ligand coordination: Synthesis, X-ray structure, and properties of mono-, di-, and polynuclear copper(II) complexes of pyridyl-containing azo ligands [J].

Das, S ;

Banerjee, P ;

Peng, SM ;

Lee, GH ;

Kim, J ;

Goswami, S .

INORGANIC CHEMISTRY, 2006, 45 (02) :562-570

[3] Rational design of 2D magnetic metal-organic coordination polymers assembled from oxalato and dipyridyl spacers [J].

Garcia-Couceiro, Urko ;

Castillo, Oscar ;

Luque, Antonio ;

Garcia-Teran, Juan P. ;

Beobide, Garikoitz ;

Roman, Pascual .

CRYSTAL GROWTH & DESIGN, 2006, 6 (08) :1839-1847

[4] Synthesis structure and luminescence of a double helical coordination polymer with a semirigid ligand:: L = N-(4-pyridylmethyl)benzimidazole [J].

Huang, Meihua ;

Liu, Ping ;

Wang, Jian ;

Chen, Yun ;

Liu, Zheng ;

Liu, Qingyan .

INORGANIC CHEMISTRY COMMUNICATIONS, 2006, 9 (09) :952-954

[5] PREPARATION, LITHIATION AND TRANSFORMATION OF N-(BENZOTRIAZOL-1-YLMETHYL) HETEROCYCLES [J].

KATRITZKY, AR ;

DREWNIAKDEYRUP, M ;

LAN, X ;

BRUNNER, F .

JOURNAL OF HETEROCYCLIC CHEMISTRY, 1989, 26 (03) :829-836

[6] A porous supramolecular architecture from a copper(II) coordination polymer with a 3D four-connected 86 net [J].

Ma, JF ;

Yang, J ;

Zheng, GL ;

Li, L ;

Liu, JF .

INORGANIC CHEMISTRY, 2003, 42 (23) :7531-7534

[7] New asymmetric N-heterocyclic-bridged mixed-valent dinuclear complexes of rhenium and ruthenium [J].

Mellace, MG ;

Fagalde, F ;

Katz, NE .

POLYHEDRON, 2003, 22 (03) :369-374

[8] Syntheses, structures and thermal stabilities of eight 1-((benzotriazol-yl)methyl)-1H-1,3-imidazole complexes based on different anions [J].

Meng, Xiangru ;

Zhu, Xiaoqing ;

Qi, Yongfang ;

Hou, Hongwei ;

Fan, Yaoting .

JOURNAL OF MOLECULAR STRUCTURE, 2009, 934 (1-3) :28-36

[9] Self-assembly of four supramolecular architectures: From 0-D to 2-D frameworks based on an unsymmetrical N-heterocyclic ligand [J].

Meng, Xiangru ;

Jin, Sizeng ;

Hou, Hongwei ;

Du, Chenxia ;

Ng, Seik Weng .

INORGANICA CHIMICA ACTA, 2009, 362 (05) :1519-1527

[10] Novel Pb and Zn coordination polymers: Synthesis, molecular structures, and third-order nonlinear optical properties [J].

Meng, XR ;

Song, YL ;

Hou, HW ;

Fan, YT ;

Li, G ;

Zhu, Y .

INORGANIC CHEMISTRY, 2003, 42 (04) :1306-1315

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