Ring Opening Metathesis Polymerization of a New Monomer Derived from a Nitroso Diels-Alder Reaction

被引：6
作者：
Subnaik, Selesha [1 ]
Sheridan, Katya [1 ]
Hobbs, Christopher E. [1 ]
机构：
[1] Sam Houston State Univ, Dept Chem, Huntsville, TX 77340 USA
来源：
MACROMOLECULAR CHEMISTRY AND PHYSICS | 2021年 / 222卷 / 14期
基金：
美国国家科学基金会;
关键词：
nitroso Diels-Alder; polymer synthesis; ring opening metathesis polymerization; VARIABLE-TEMPERATURE ROMP; ONE-POT SYNTHESIS; COPOLYMERS; POLYPENTENAMERS; DECOMPOSITION; MOLYBDENUM; CATALYSTS; GRUBBS; ACIDS; CORE;
D O I：
10.1002/macp.202100098
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A nitroso Diels-Alder (NDA) reaction between cyclopentadiene and an in situ generated nitroso compound leads to a new heterocyclic monomer for ring opening metathesis polymerization (ROMP) reactions. This monomer could be polymerized in the presence of Grubbs-third generation initiator with good control over Mn and decent D values. The resulting isoxazolidine-containing material could undergo further hydrogenation, deprotection, and modification with Dansyl chloride as well as ring opening to provide an amino-and hydroxyl-decorated "polyolefin."
引用
收藏
页数：6
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