Ring Opening Metathesis Polymerization of a New Monomer Derived from a Nitroso Diels-Alder Reaction

被引：6

作者：

Subnaik, Selesha ^{[1
]}

Sheridan, Katya ^{[1
]}

Hobbs, Christopher E. ^{[1
]}

机构：

[1] Sam Houston State Univ, Dept Chem, Huntsville, TX 77340 USA

来源：

MACROMOLECULAR CHEMISTRY AND PHYSICS | 2021年 / 222卷 / 14期

基金：

美国国家科学基金会;

关键词：

nitroso Diels-Alder; polymer synthesis; ring opening metathesis polymerization; VARIABLE-TEMPERATURE ROMP; ONE-POT SYNTHESIS; COPOLYMERS; POLYPENTENAMERS; DECOMPOSITION; MOLYBDENUM; CATALYSTS; GRUBBS; ACIDS; CORE;

D O I：

10.1002/macp.202100098

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A nitroso Diels-Alder (NDA) reaction between cyclopentadiene and an in situ generated nitroso compound leads to a new heterocyclic monomer for ring opening metathesis polymerization (ROMP) reactions. This monomer could be polymerized in the presence of Grubbs-third generation initiator with good control over Mn and decent D values. The resulting isoxazolidine-containing material could undergo further hydrogenation, deprotection, and modification with Dansyl chloride as well as ring opening to provide an amino-and hydroxyl-decorated "polyolefin."

引用

页数：6

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