Improving photocatalytic activity under visible light over a novel food wastes biochar-based BiOBr nanocomposite

被引:14
作者
Zhang, Xiaoqian [1 ,2 ,3 ]
Wu, Yixiao [1 ]
Giwa, Abdulmoseen Segun [4 ]
Xiong, Juxia [1 ]
Huang, Shaobin [1 ]
Niu, Lishan [1 ]
机构
[1] South China Univ Technol, Higher Educ Mega Ctr, Sch Environm & Energy, Guangzhou 510006, Peoples R China
[2] South China Univ Technol, Higher Educ Mega Ctr, Minist Educ, Key Lab Pollut Control & Ecosyst Restorat Ind Clu, Guangzhou 510006, Peoples R China
[3] Engn South China Univ, State Key Lab Pulp & Paper, Guangzhou 510640, Peoples R China
[4] Yangtze Normal Univ, Green Intelligence Environm Sch, Chongqing, Peoples R China
基金
中国国家自然科学基金; 国家重点研发计划;
关键词
Carbonaceous material; Photodegradation; Oxygen functional groups; Persistent free radicals; Z-SCHEME HETEROJUNCTION; SOLVOTHERMAL SYNTHESIS; PYROLYSIS TEMPERATURE; AQUEOUS-SOLUTION; CARBON; DEGRADATION; PERSULFATE; MECHANISM; BIOMASS; WATER;
D O I
10.1016/j.chemosphere.2022.134152
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Biochar (C) applied in synthesizing photocatalysts to eliminate water pollution has been intensively investigated. Herein we report the first use of biochar pyrolyzed from food wastes at 400 C (400C) and 700 C to construct C/ BiOBr composites via a facile hydrolysis approach. Photocatalytic performances could be significantly improved by choosing the appropriate carbonization temperature and adjusting the content of C in C/BiOBr composites. The prepared 1%400C/BiOBr exhibited the best photodegradation capacity towards methylene orange (20 mg/ L) and tetracycline (50 mg/L). A series of characterization results illustrated that smooth structure and surface properties (oxygen functional groups and persistent free radicals) of 400C played an important role in enhancing the photocatalytic activities. Mechanism exploration suggested that h(+) and O-2(-)& nbsp;were the main active species thus contributing to photodegradation. This study provided a new insight into utilization of biochar derived from food wastes in photocatalysis and environmental remediation.
引用
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页数:11
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