Improved rhodium hydrogenation catalysts immobilized on oxidic supports

被引：53

作者：

Merckle, C ^{[1
]}

Blümel, J ^{[1
]}

机构：

[1] Univ Heidelberg, Dept Organ Chem, D-69120 Heidelberg, Germany

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2003年 / 345卷 / 05期

关键词：

alkene reduction; catalytic hydrogenation; immobilization; P ligands; rhodium; silica; solid-state NMR;

D O I：

10.1002/adsc.200202197

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Wilkinson-type rhodium hydrogenation catalysts immobilized on oxidic supports via mono- and bidentate phosphine linkers have been studied by P-31 solid-state NMR, and their recycling stability and lifetime with respect to hydrogenation of 1-dodecene, 2-cyclohexen-1-one, and 4-bromostyrene have been improved substantially.

引用

页码：584 / 588

页数：5

共 22 条

[1] Reactions of ethoxysilanes with silica: A solid-state NMR study [J].

Behringer, KD ;

Blumel, J .

JOURNAL OF LIQUID CHROMATOGRAPHY & RELATED TECHNOLOGIES, 1996, 19 (17-18) :2753-2765

[2] Immobilization of carbonylnickel complexes: A solid-state NMR study [J].

Behringer, KD ;

Blumel, J .

INORGANIC CHEMISTRY, 1996, 35 (07) :1814-1819

[3] SUSPENSION NMR-SPECTROSCOPY OF PHOSPHINES AND CARBONYLNICKEL COMPLEXES IMMOBILIZED ON SILICA [J].

BEHRINGER, KD ;

BLUMEL, J .

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1995, 50 (11) :1723-1728

[4] Immobilization and chelation of metal complexes with bifunctional phosphine ligands: A solid-state NMR study [J].

Behringer, KD ;

Blumel, J .

CHEMICAL COMMUNICATIONS, 1996, (05) :653-654

[5]

BLUMEL J, 1995, J AM CHEM SOC, V117, P2112

[6]

BLUMEL J, 1994, INORG CHEM, V33, P5050

[7]

Chaloner P A., 1994, Homogeneous Hydrogenation, DOI [DOI 10.1007/978-94-017-1791-5, 10.1007/978-94-017-1791-5]

[8]

CLARK JH, 1994, SUPPORTED REAGENTS O

[9]

Cornils B., 1996, APPL HOMOGENEOUS CAT

[10]

Duncan T. M., 1990, COMPILATION CHEM SHI

← 1 2 3 →