A porous chiral framework of coordinated 1,3,5-benzenetricarboxylate: quadruple interpenetration of the (10,3)-a network

被引：216
|
作者：
Kepert, CJ [1 ]
Rosseinsky, MJ [1 ]
机构：
[1] Univ Oxford, Inorgan Chem Lab, Oxford OX1 3QR, England
来源：
CHEMICAL COMMUNICATIONS | 1998年 / 01期
关键词：
D O I：
10.1039/a705336c
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The chiral and porous cubic coordination polymer Ni-3(btc)(2)(py)(6)(eg)(6).xeg.yH(2)O (btc = 1,3,5-benzenetricarboxylate, py = pyridine, eg = ethylene glycol, x approximate to 3, y approximate to 4) is based on the interpenetration of four independent (10,3)-a networks, and contains large interconnected cavities with diameter 16 Angstrom which may be desolvated without irreversibly destroying the porous framework structure.
引用
收藏
页码：31 / 32
页数：2
相关论文
共 50 条
  • [1] New 3-D chiral framework of indium with 1,3,5-benzenetricarboxylate
    Lin, ZZ
    Jiang, FL
    Chen, L
    Yuan, DQ
    Hong, MC
    INORGANIC CHEMISTRY, 2005, 44 (01) : 73 - 76
  • [2] Hydrogen bond-directed hexagonal frameworks based on coordinated 1,3,5-benzenetricarboxylate
    Kepert, CJ
    Prior, TJ
    Rosseinsky, MJ
    JOURNAL OF SOLID STATE CHEMISTRY, 2000, 152 (01) : 261 - 270
  • [3] Synthesis, Structures and Electrochemical Properties of Lithium 1,3,5-Benzenetricarboxylate Complexes
    Cheng, Pei-Chi
    Li, Bing-Han
    Tseng, Feng-Shuen
    Liang, Po-Ching
    Lin, Chia-Her
    Liu, Wei-Ren
    POLYMERS, 2019, 11 (01)
  • [4] Negative Thermal Expansion in the Metal-Organic Framework Material Cu3(1,3,5-benzenetricarboxylate)2
    Wu, Yue
    Kobayashi, Atsushi
    Halder, Gregory J.
    Peterson, Vanessa K.
    Chapman, Karena W.
    Lock, Nina
    Southon, Peter D.
    Kepert, Cameron J.
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (46) : 8929 - 8932
  • [5] Novel hybrid porous 3D networks of lead(II) diphosphonate and triphosphonate containing 1,3,5-benzenetricarboxylate
    Song, JL
    Mao, JG
    Sun, YQ
    Clearfield, A
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2003, (23) : 4218 - 4226
  • [6] Double Interpenetration in a Chiral Three-Dimensional Magnet with a (10,3)-a Structure
    Grancha, Thais
    Mon, Marta
    Lloret, Francesc
    Ferrando-Soria, Jesus
    Journaux, Yves
    Pasan, Jorge
    Pardo, Emilio
    INORGANIC CHEMISTRY, 2015, 54 (18) : 8890 - 8892
  • [7] A new zinc-1,3,5-benzenetricarboxylate framework integrated three distinct subunits (SBUs)
    Xie, Yi-Ming
    JOURNAL OF SOLID STATE CHEMISTRY, 2013, 202 : 116 - 120
  • [8] Guest-Host Complexes of TCNQ and TCNE with Cu3(1,3,5-benzenetricarboxylate)2
    Usov, Pavel M.
    Jiang, Henry
    Chevreau, Hubert
    Peterson, Vanessa K.
    Leong, Chanel F.
    D'Alessandro, Deanna M.
    JOURNAL OF PHYSICAL CHEMISTRY C, 2017, 121 (47): : 26330 - 26339
  • [9] DETERMINATION OF IODIDE BY SUPPRESSED ION CHROMATOGRAPHY USING 1,3,5-BENZENETRICARBOXYLATE ELUENT
    MIURA, Y
    KOH, T
    BUNSEKI KAGAKU, 1992, 41 (07) : 331 - 335
  • [10] Remarkable solvent-size effects in constructing novel porous 1,3,5-benzenetricarboxylate metal-organic frameworks
    Hao, Xiang-Rong
    Wang, Xin-Long
    Shao, Kui-Zhan
    Yang, Guang-Sheng
    Su, Zhong-Min
    Yuan, Gang
    CRYSTENGCOMM, 2012, 14 (17): : 5596 - 5603
12345