Gold(I) complexes with amine ligands .1. A novel stoichiometry for chlorogold(I) complexes: Structure of L4Au3Cl3 (L = pyrrolidine)

被引：26

作者：

Jones, PG

Ahrens, B

机构：

[1] Institut für Anorganische, Analytische Chemie der Technischen Universität, D-38023 Braunschweig

来源：

CHEMISCHE BERICHTE-RECUEIL | 1997年 / 130卷 / 12期

关键词：

amines; gold(I);

D O I：

10.1002/cber.19971301217

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction between (tht)AuCl (tht = tetrahydrothiophene) and neat pyrrolidine (L) leads to the compound L4Au3Cl3. An X-ray structure determination reveals the presence of molecules LAuCl and ions L2Au+ and Cl-, in the ratio 2:1:1. The packing is characterised by Au...Au contacts and N-H...Cl- hydrogen bonds.

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页码：1813 / 1814

页数：2

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