Multiresponsive Donor-Acceptor Stenhouse Adduct: Opportunities Arise from a Diamine Donor

被引：22
作者：
Cai, You-De [1 ]
Chen, Tian-Yang [1 ]
Chen, Xiu Qin [1 ]
Bao, Xin [1 ]
机构：
[1] Nanjing Univ Sci & Technol, Sch Chem Engn, Nanjing 210094, Jiangsu, Peoples R China
来源：
ORGANIC LETTERS | 2019年 / 21卷 / 18期
基金：
中国国家自然科学基金;
关键词：
VISIBLE-LIGHT; PHOTOSWITCHES;
D O I：
10.1021/acs.orglett.9b02753
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A new donor-acceptor Stenhouse adduct based on a N,N,N'-trimethylethylenediamine donor has been reported. An unprecedented isomer has been isolated, and rich conversions between three isomers have been achieved upon visible-light irradiation or base/acid stimuli. The drastic color change associated with structural conversion has been utilized to selectively sense volatile primary amines as well as high-charged hard Lewis acids (Sc3+, Ti4+, Cr3+, and Al3+).
引用
收藏
页码：7445 / 7449
页数：5
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