Expected and unexpected outcomes of a heteroborane isomerisation

被引：23

作者：

Dunn, S ^{[1
]}

Rosair, GM ^{[1
]}

Weller, AS ^{[1
]}

Welch, AJ ^{[1
]}

机构：

[1] Heriot Watt Univ, Dept Chem, Edinburgh EH14 4AS, Midlothian, Scotland

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 10期

关键词：

D O I：

10.1039/a709061g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Gentle thermolysis of compound 1, an intermediate in the isomerisation of an overcrowded icosahedral carbametallaborane, surprisingly yields two rearranged products, compound 2 (expected from theory) and compound 3 (unexpected).

引用

页码：1065 / 1066

页数：2

共 5 条

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Rosair, GM ;

Welch, AJ ;

Weller, AS ;

Zahn, SK .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1997, 536 (1-2) :299-308

[3]

ROSAIR GM, 1998, IN PRESS ORGANOMETAL

[4] REARRANGEMENT MECHANISMS OF B12H12(2-) AND C2B10H12 [J].

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[5] Synthesis and reactivity of 7,9-diphenyl-nido-carbaundecaboranes: Rearrangement processes in carbaplatinaboranes revisited [J].

Welch, AJ ;

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JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1997, (07) :1205-1212

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