Hydrogenation of carbon dioxide: a comparison of different types of active catalysts

被引：17
作者：
Kustov, Leonid M. [1 ,2 ]
Tarasov, Andrei L. [1 ]
机构：
[1] Russian Acad Sci, ND Zelinsky Inst Organ Chem, Moscow 119991, Russia
[2] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119991, Russia
来源：
MENDELEEV COMMUNICATIONS | 2014年 / 24卷 / 06期
基金：
俄罗斯科学基金会;
关键词：
TRANSFORMATION; SEQUESTRATION; METHANATION; CO2;
D O I：
10.1016/j.mencom.2014.11.012
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Comparison of the activity and CO selectivity of four principally different types of catalysts in CO2 hydrogenation, namely, LaNi5, Rh/ZnO-CuO, fumed Fe2O3-K2O-Al2O3 and Au/SO4-ZrO2, in the entire temperature range at an atmospheric pressure was performed. The use of the intermetallide LaNi5 catalyst provides an enhanced activity in CO2 hydrogenation with prevailing methane formation, while other catalysts demonstrated predominant formation of CO.
引用
收藏
页码：349 / 350
页数：2
相关论文
共 12 条
  • [1] METHANATION OF CARBON-DIOXIDE OVER LANI(4)X-TYPE INTERMETALLIC COMPOUNDS AS CATALYST PRECURSOR
    ANDO, H
    FUJIWARA, M
    MATSUMURA, Y
    MIYAMURA, H
    TANAKA, H
    SOUMA, Y
    [J]. JOURNAL OF ALLOYS AND COMPOUNDS, 1995, 223 (01) : 139 - 141
  • [2] Catalytic hydrogenation of carbon dioxide over LaNi5 activated during the reaction
    Ando, H
    Fujiwara, M
    Matsumura, Y
    Tanaka, M
    Souma, Y
    [J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1999, 144 (01) : 117 - 122
  • [3] METHANATION OF CARBON-DIOXIDE OVER LANI(4)X TYPE CATALYSTS
    ANDO, H
    FUJIWARA, M
    MATSUMURA, Y
    MIYAMURA, H
    SOUMA, Y
    [J]. ENERGY CONVERSION AND MANAGEMENT, 1995, 36 (6-9) : 653 - 656
  • [4] Gold catalysts supported on ceria and ceria-alumina for water-gas shift reaction
    Andreeva, D
    Ivanova, I
    Ilieva, L
    Abrashev, MV
    [J]. APPLIED CATALYSIS A-GENERAL, 2006, 302 (01) : 127 - 132
  • [5] Golomb DS, 2003, SCIENCE, V301, P1326, DOI 10.1126/science.301.5638.1326
  • [6] Highly effective conversion of carbon dioxide to valuable compounds on composite catalysts
    Inui, T
    [J]. CATALYSIS TODAY, 1996, 29 (1-4) : 329 - 337
  • [7] Kuperman A., 2005, Method for making hydrogen using a gold containing water-gas shift catalyst, Patent No. [WO 2005 005032, 2005005032]
  • [8] A guide to CO2 sequestration
    Lackner, KS
    [J]. SCIENCE, 2003, 300 (5626) : 1677 - 1678
  • [9] Transformation of carbon dioxide
    Sakakura, Toshiyasu
    Choi, Jun-Chul
    Yasuda, Hiroyuki
    [J]. CHEMICAL REVIEWS, 2007, 107 (06) : 2365 - 2387
  • [10] Problem of hydrogen storage and prospective uses of hydrides for hydrogen accumulation
    Tarasov, B. P.
    Lototskii, M. V.
    Yartys, V. A.
    [J]. RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2007, 77 (04) : 694 - 711
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