Hydrogenation of carbon dioxide: a comparison of different types of active catalysts

被引：17

作者：

Kustov, Leonid M. ^{[1
,2
]}

Tarasov, Andrei L. ^{[1
]}

机构：

[1] Russian Acad Sci, ND Zelinsky Inst Organ Chem, Moscow 119991, Russia

[2] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119991, Russia

来源：

MENDELEEV COMMUNICATIONS | 2014年 / 24卷 / 06期

基金：

俄罗斯科学基金会;

关键词：

TRANSFORMATION; SEQUESTRATION; METHANATION; CO2;

D O I：

10.1016/j.mencom.2014.11.012

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Comparison of the activity and CO selectivity of four principally different types of catalysts in CO2 hydrogenation, namely, LaNi5, Rh/ZnO-CuO, fumed Fe2O3-K2O-Al2O3 and Au/SO4-ZrO2, in the entire temperature range at an atmospheric pressure was performed. The use of the intermetallide LaNi5 catalyst provides an enhanced activity in CO2 hydrogenation with prevailing methane formation, while other catalysts demonstrated predominant formation of CO.

引用

页码：349 / 350

页数：2

共 12 条

[1] METHANATION OF CARBON-DIOXIDE OVER LANI(4)X-TYPE INTERMETALLIC COMPOUNDS AS CATALYST PRECURSOR [J].

ANDO, H ;

FUJIWARA, M ;

MATSUMURA, Y ;

MIYAMURA, H ;

TANAKA, H ;

SOUMA, Y .

JOURNAL OF ALLOYS AND COMPOUNDS, 1995, 223 (01) :139-141

[2] Catalytic hydrogenation of carbon dioxide over LaNi5 activated during the reaction [J].

Ando, H ;

Fujiwara, M ;

Matsumura, Y ;

Tanaka, M ;

Souma, Y .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1999, 144 (01) :117-122

[3] METHANATION OF CARBON-DIOXIDE OVER LANI(4)X TYPE CATALYSTS [J].

ANDO, H ;

FUJIWARA, M ;

MATSUMURA, Y ;

MIYAMURA, H ;

SOUMA, Y .

ENERGY CONVERSION AND MANAGEMENT, 1995, 36 (6-9) :653-656

[4] Gold catalysts supported on ceria and ceria-alumina for water-gas shift reaction [J].

Andreeva, D ;

Ivanova, I ;

Ilieva, L ;

Abrashev, MV .

APPLIED CATALYSIS A-GENERAL, 2006, 302 (01) :127-132

[5]

Golomb DS, 2003, SCIENCE, V301, P1326, DOI 10.1126/science.301.5638.1326

[6] Highly effective conversion of carbon dioxide to valuable compounds on composite catalysts [J].

Inui, T .

CATALYSIS TODAY, 1996, 29 (1-4) :329-337

[7]

Kuperman A., 2005, Method for making hydrogen using a gold containing water-gas shift catalyst, Patent No. [WO 2005 005032, 2005005032]

[8] A guide to CO2 sequestration [J].

Lackner, KS .

SCIENCE, 2003, 300 (5626) :1677-1678

[9] Transformation of carbon dioxide [J].

Sakakura, Toshiyasu ;

Choi, Jun-Chul ;

Yasuda, Hiroyuki .

CHEMICAL REVIEWS, 2007, 107 (06) :2365-2387

[10] Problem of hydrogen storage and prospective uses of hydrides for hydrogen accumulation [J].

Tarasov, B. P. ;

Lototskii, M. V. ;

Yartys, V. A. .

RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2007, 77 (04) :694-711

← 1 2 →