General and efficient methodology for the Suzuki-Miyaura reaction in technical grade 2-propanol

被引：50

作者：

Navarro, O

Oonishi, Y

Kelly, RA

Stevens, ED

Briel, O

Nolan, SP ^{[1
]}

机构：

[1] Univ New Orleans, Dept Chem, New Orleans, LA 70148 USA

[2] Umicore AG&Co KG, D-63403 Hanau, Germany

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2004年 / 689卷 / 23期

基金：

美国国家科学基金会; 日本学术振兴会;

关键词：

Suzuki-Miyaura reaction; palladium; catalysis; N-heterocyclic carbene;

D O I：

10.1016/j.jorganchem.2004.04.001

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction. profile of a series of palladium-based catalysts was examined in the Suzuki-Miyaura reaction using technical grade 2-propanol as solvent and potassium t-butoxide as base. The results generally show high activity. The method allows for the coupling of electron-rich aryl chlorides with sterically hindered aryl boronic acids to produce tri-ortho-substituted biaryls in high yields using very mild conditions and short reaction times. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：3722 / 3727

页数：6

共 50 条

[41] Efficient Pd(OAc)2/pyrimidine catalytic system for Suzuki-Miyaura cross-coupling reaction
Li, JH
Zhang, XD
Xie, YX
SYNLETT, 2005, (12) : 1897 - 1900
[42] Pd nanoparticles embedded in mesoporous carbon: A highly efficient catalyst for Suzuki-Miyaura reaction
Zhong, Lin
Chokkalingam, Anand
Cha, Wang S.
Lakhi, Kripal S.
Su, Xiangyang
Lawrence, Geoffrey
Vinu, Ajayan
CATALYSIS TODAY, 2015, 243 : 195 - 198
[43] Highly efficient palladium catalysts supported on nitrogen contained polymers for Suzuki-Miyaura reaction
Geng, Longfei
Li, Yan
Qi, Zhengliang
Fan, Haipeng
Zhou, Zhicheng
Chen, Rizhi
Wang, Yong
Huang, Jun
CATALYSIS COMMUNICATIONS, 2016, 82 : 24 - 28
[44] Metallomicelles of palladium(II) complexes as efficient catalysts for the Suzuki-Miyaura reaction in neat water
Liu, Yan
Ma, Xiaowei
Xie, Jianwei
Liu, Ping
Dai, Bin
He, Ren
APPLIED ORGANOMETALLIC CHEMISTRY, 2013, 27 (08) : 494 - 498
[45] An efficient catalyst for Suzuki-Miyaura coupling reaction in aqueous medium under aerobic conditions
Chen, CL
Liu, YH
Peng, SM
Liu, ST
TETRAHEDRON LETTERS, 2005, 46 (03) : 521 - 523
[46] A Versatile Method for Preparation of BrCOFs Aerogels and Efficient Functionalization via Suzuki-Miyaura Reaction
Wang, Qiaomu
Wang, Peng
Wang, Yandong
Xu, Yang
Xu, Haocheng
Xi, Kai
SMALL METHODS, 2024,
[47] Efficient synthesis of differently substituted triarylpyridines with the Suzuki-Miyaura cross-coupling reaction
Blachut, Dariusz
Szawkalo, Joanna
Pomaranski, Piotr
Roszkowski, Piotr
Maurin, Jan K.
Czarnocki, Zbigniew
ARKIVOC, 2017, : 369 - 389
[48] Palladium Supported on Functionalized Mesoporous Silica as an Efficient Catalyst for Suzuki-Miyaura Coupling Reaction
Zhang, Guoheng
Wang, Peiyu
Wei, Xiufang
CATALYSIS LETTERS, 2013, 143 (11) : 1188 - 1194
[49] Highly efficient Suzuki-Miyaura coupling of heterocyclic substrates through rational reaction design
Fleckenstein, Christoph A.
Plenio, Herbert
CHEMISTRY-A EUROPEAN JOURNAL, 2008, 14 (14) : 4267 - 4279
[50] Synthesis and Characterization of Biguanide and Biguanidium Surfactants for Efficient and Recyclable Application in the Suzuki-Miyaura Reaction
Fortun, Solene
Schmitzer, Andreea R.
ACS OMEGA, 2018, 3 (02): : 1889 - 1896

← 1 2 3 4 5 →