General and efficient methodology for the Suzuki-Miyaura reaction in technical grade 2-propanol

被引：50
作者：
Navarro, O
Oonishi, Y
Kelly, RA
Stevens, ED
Briel, O
Nolan, SP [1 ]
机构：
[1] Univ New Orleans, Dept Chem, New Orleans, LA 70148 USA
[2] Umicore AG&Co KG, D-63403 Hanau, Germany
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2004年 / 689卷 / 23期
基金：
日本学术振兴会; 美国国家科学基金会;
关键词：
Suzuki-Miyaura reaction; palladium; catalysis; N-heterocyclic carbene;
D O I：
10.1016/j.jorganchem.2004.04.001
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction. profile of a series of palladium-based catalysts was examined in the Suzuki-Miyaura reaction using technical grade 2-propanol as solvent and potassium t-butoxide as base. The results generally show high activity. The method allows for the coupling of electron-rich aryl chlorides with sterically hindered aryl boronic acids to produce tri-ortho-substituted biaryls in high yields using very mild conditions and short reaction times. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码：3722 / 3727
页数：6
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