General and efficient methodology for the Suzuki-Miyaura reaction in technical grade 2-propanol

被引：50

作者：

Navarro, O

Oonishi, Y

Kelly, RA

Stevens, ED

Briel, O

Nolan, SP ^{[1
]}

机构：

[1] Univ New Orleans, Dept Chem, New Orleans, LA 70148 USA

[2] Umicore AG&Co KG, D-63403 Hanau, Germany

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2004年 / 689卷 / 23期

基金：

日本学术振兴会; 美国国家科学基金会;

关键词：

Suzuki-Miyaura reaction; palladium; catalysis; N-heterocyclic carbene;

D O I：

10.1016/j.jorganchem.2004.04.001

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction. profile of a series of palladium-based catalysts was examined in the Suzuki-Miyaura reaction using technical grade 2-propanol as solvent and potassium t-butoxide as base. The results generally show high activity. The method allows for the coupling of electron-rich aryl chlorides with sterically hindered aryl boronic acids to produce tri-ortho-substituted biaryls in high yields using very mild conditions and short reaction times. (C) 2004 Elsevier B.V. All rights reserved.

引用

收藏

页码：3722 / 3727

页数：6

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