(meso-5,7,7,12,14,14-Hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene)copper(II) bis[O,O′-bis(4-methylphenyl) dithiophosphate]

被引：6

作者：

He, Lin-Xin ^{[1
]}

Zou, Li-Ke ^{[1
]}

Xie, Bin ^{[1
]}

Xiang, Yang-Guang ^{[1
]}

Feng, Jian-Shen ^{[1
]}

机构：

[1] Sichuan Univ Sci & Engn, Coll Chem & Pharmaceut Engn, Zigong 643000, Sichuan, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷

关键词：

X-RAY; DITHIOPHOSPHATES;

D O I：

10.1107/S1600536810009815

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, [Cu(C(16)H(32)N(4))](C(14)H(14)O(2)PS(2))(2) or [Cu(trans[14] dien)][S(2)P(OC(6)H(4)Me-(4))(2)](2), where trans[14] dien is meso-5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene, was obtained by the reaction of [Cu(trans[14] dien)](ClO(4))(2) and [(C(2)H(5))(2)NH](2) [S(2)P(OC(6)H(4)-Me-4)(2)](2). The Cu(II) atom lies on a centre of inversion and possesses a relatively undistorted square-planar coordination arrangement with four N atoms of the macrocyclic tetramine trans[14] dien [Cu-N = 1.9716 (19) and 2.0075 (19) angstrom]. The two uncoordinated [(4-MeC(6)H(4)O)(2)PS(2)](-) groups act as counter-ions to balance the charge and interact with the [Cu(trans[14]dien)](2+) complex cation through N-H center dot center dot center dot S hydrogen bonds.

引用

页码：M428 / U856

页数：10

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