Direct production of hydrogen peroxide from oxygen and hydrogen applying membrane-permeation mechanism

被引：23

作者：

Inoue, Tomoya ^{[1
]}

Tanaka, Yusuke ^{[1
,2
]}

Tanaka, David A. Pacheco ^{[1
]}

Suzuki, Toshishige M. ^{[1
]}

Sato, Koichi ^{[1
]}

Nishioka, Masateru ^{[1
]}

Hamakawa, Satoshi ^{[1
]}

Mizukami, Fujio ^{[1
]}

机构：

[1] Natl Inst Adv Ind Sci & Technol, Res Ctr Compact Chem Proc, Tsukuba, Ibaraki, Japan

[2] Tohoku Univ, Dept Chem, Grad Sch Sci, Sendai, Miyagi 980, Japan

来源：

CHEMICAL ENGINEERING SCIENCE | 2010年 / 65卷 / 01期

关键词：

Hydrogen peroxide; Direct synthesis; Palladium membrane; Hydrogen permeation; DIRECT HYDROXYLATION; CATALYTIC MEMBRANES; PALLADIUM MEMBRANE; ALLOY MEMBRANES; LIQUID-PHASE; H2O2; O-2; H-2; REACTORS; MICROREACTORS;

D O I：

10.1016/j.ces.2009.06.002

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Direct synthesis of hydrogen peroxide is conducted using a palladium membrane reactor. The palladium membrane is prepared on the external surface of the porous a-alumina tubing, by electroless plating (ELP) or chemical vapor deposition (CVD). Thus prepared membrane is immersed into aqueous reaction solution. Hydrogen is supplied from inside of the palladium membrane, while oxygen was bubbled in the reaction solution. Both reacted at the surface of the membrane to produce hydrogen peroxide. Hydrogen peroxide is produced steadily for more than 80 h and the selectivity based on the amount of reacted hydrogen was estimated to be ca. 50%. The reactor performance is investigated in correlation with membrane properties and the hydrogen/oxygen supply pressures. (C) 2009 Elsevier Ltd. All rights reserved.

引用

页码：436 / 440

页数：5

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