Synthesis and competency of a tartrate-derived dicationic solid-liquid phase-transfer catalyst

被引：18

作者：

Rueffer, ME ^{[1
]}

Fort, LK ^{[1
]}

MacFarland, DK ^{[1
]}

机构：

[1] Gettysburg Coll, Dept Chem, Gettysburg, PA 17325 USA

来源：

TETRAHEDRON-ASYMMETRY | 2004年 / 15卷 / 20期

关键词：

D O I：

10.1016/j.tetasy.2004.09.004

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new asymmetric phase-transfer catalyst is described, along with a new, flexible synthetic scheme using a tartaric acid chloride. Alkylations and Michael reactions on a glycine imino ester show the new catalyst to be an effective phase-transfer catalyst with limited enantioselectivity. (C) 2004 Published by Elsevier Ltd.

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页码：3297 / 3300

页数：4

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