Iodine-Catalyzed Chemoselective Hydroamination Reaction Using 5-Mercaptotetrazoles Derivatives

被引：10
作者：
Siddaraju, Yogesh [1 ]
Prabhu, Kandikere Ramaiah [1 ]
机构：
[1] Indian Inst Sci, Dept Organ Chem, Bangalore 560012, Karnataka, India
来源：
ACS OMEGA | 2018年 / 3卷 / 05期
关键词：
DEHYDROGENATIVE COUPLING REACTION; DIMETHYL-SULFOXIDE; C-H; ALKENES; HYDROTHIOLATION; HYDROARYLATION; SULFENYLATION; STYRENES; OXIDANT; KETONES;
D O I：
10.1021/acsomega.8b00499
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Metal-free chemoselective hydroamination of styrene derivatives has been achieved with high chemo-selectivity over sulfenylation of 1H-tetrazole-5-thiol using a catalytic amount of iodine. The scope of this methodology has been extended for the hydroamination of a-substituted styrene derivatives. This reaction involves a single-step C-N-bond formation under atom economical process. This eco-friendly method uses readily available and inexpensive iodine in a catalytic amount.
引用
收藏
页码：4908 / 4917
页数：10
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