Thermodynamic viscous flow activation characteristics for n-alkanes and n-alkenes-1

被引：1
|
作者：
Renskii, IA [1 ]
Rudnitskaya, AA [1 ]
Fialkov, YY [1 ]
机构：
[1] Natl Tech Univ Ukraine, Dept Chem, UA-03056 Kiev, Ukraine
来源：
JOURNAL OF MOLECULAR LIQUIDS | 2003年 / 105卷 / 01期
关键词：
viscosity; n-alkanes; n-alkenes-1; thermodynamic activation; characteristics;
D O I：
10.1016/S0167-7322(03)00013-8
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The paper presents viscous flow activation parameters for n-alkanes and n-alkens-1, calculated from the equation of transition state theory. Transmission coefficients and true values of the entropy of viscous flow activation of n-alkanes and n-alkens-1 have been calculated from kinetic compensation effects using theses of the Shakhparonov general theory of fluid viscosity. Analysis of the data obtained allows one to conclude that the intermolecular interactions caused by weak Csigma-H(...)Csigma bonds are more pronounced is saturated hydrocarbons. (C) 2003 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：73 / 78
页数：6
相关论文
共 50 条
  • [1] Diffusion of alkenes in N-alkanes
    Kowert, BA
    Turner, RM
    Caldwell, CVC
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2005, 229 : U452 - U452
  • [2] A SEGMENT MODEL FOR SOLUTIONS OF N-ALKANES AND N-ALKENES
    CRUICKSHANK, AJ
    GAINEY, BW
    HICKS, CP
    LETCHER, TM
    YOUNG, CL
    TRANSACTIONS OF THE FARADAY SOCIETY, 1969, 65 (561P): : 2356 - +
  • [3] THERMODYNAMIC PROPERTIES OF BINARY MIXTURES OF N-ALKANES
    ORWOLL, RA
    FLORY, PJ
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1967, 89 (26) : 6822 - +
  • [4] Thermodynamic properties of n-alkanes in porous graphite
    Espeau, P
    White, JW
    JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1997, 93 (17): : 3197 - 3200
  • [5] Characteristics of n-alkanes in the Taipei aerosol
    Grad. Inst. of Environmental Health, National Taiwan University, Taipei, Taiwan
    Journal of Aerosol Science, 1998, 29 (SUPPL 1):
  • [6] Thermodynamic interactions in binary mixtures of 1-chloronaphthalene with n-alkanes
    Aminabhavi, TM
    Banerjee, K
    INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 2001, 40 (01): : 53 - 64
  • [7] PREDICTION OF THERMODYNAMIC PROPERTIES OF TERNARY HYDROCARBON MIXTURES CONTAINING OLEFINS .1. 1-ALKENES + BENZENE + N-ALKANES
    VILLAMANAN, MA
    KEHIAIAN, HV
    FLUID PHASE EQUILIBRIA, 1988, 42 : 165 - 172
  • [8] PHASE BEHAVIOUR OF N-ALKANES AND POLYETHYLENE - A THERMODYNAMIC STUDY
    ATKINSON, CM
    RICHARSO.MJ
    TRANSACTIONS OF THE FARADAY SOCIETY, 1969, 65 (559P): : 1749 - &
  • [9] STANDARD CHEMICAL THERMODYNAMIC PROPERTIES OF PERFLUORO N-ALKANES
    WEN, CM
    JOURNAL OF THE CHINESE CHEMICAL SOCIETY, 1990, 37 (01) : 55 - 62
  • [10] Thermodynamic viscous flow activation characteristics of the n-aliphatic derivatives of cyclohexane and benzene
    Renskii, IA
    Rudnitskaya, AA
    Fialkov, YY
    JOURNAL OF MOLECULAR LIQUIDS, 2004, 115 (2-3) : 89 - 91
12345