Analysis of lanthanide π-complexes containing N, P, and As atoms

被引：0

作者：

Blatova, OA ^{[1
]}

Blatov, VA ^{[1
]}

Serezhkin, VN ^{[1
]}

机构：

[1] Samara State Univ, Samara 443086, Russia

来源：

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2003年 / 29卷 / 01期

基金：

俄罗斯基础研究基金会;

关键词：

Oxidation; Physical Chemistry; Crystal Structure; Structure Feature; Oxidation State;

D O I：

10.1023/A:1021842917491

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A sampling comprising 92 LnC(n)H(m)Q(k), pi-complexes (Ln = Sc, Y, or lanthanides; Q = N, P, As) was used to analyze the influence of the nature, the oxidation state, and the coordination number of the central Ln atom and the nature of the Q atom on the parameters of the lanthanide action area. The effect of steric factors on the stability of complex groups and on the presence (or absence) of agostic interactions in the structures of these complexes was studied. A number of crystal structure features found previously for lanthanide R-complexes of a different stoichiometric composition was confirmed for the structures of the given complexes.

引用

页码：38 / 45

页数：8