Metal-Free Photochemical C-Se Cross-Coupling of Aryl Halides with Diselenides

被引：15
作者：
Wang, Ruizhe [1 ]
Wang, Xinyu [2 ]
Mao, Shuai [2 ]
Zhao, Yahao [2 ]
Yuan, Bo [2 ]
Yang, Xue-Yan [2 ]
Li, Jianjun [1 ]
Chen, Zhengkai [3 ]
机构：
[1] Xi An Jiao Tong Univ, Sch Chem, MOE Key Lab Nonequilibrium Synth & Modulat Conden, Xian 710049, Shaanxi, Peoples R China
[2] Xi An Jiao Tong Univ, Sch Pharm, Dept Med Chem, Xian 710061, Shaanxi, Peoples R China
[3] Zhejiang Sci Tech Univ, Dept Chem, Key Lab Surface & Interface Sci Polymer Mat Zheji, Hangzhou 310018, Peoples R China
来源：
ADVANCED SYNTHESIS & CATALYSIS | 2022年 / 364卷 / 09期
基金：
中国博士后科学基金; 中国国家自然科学基金;
关键词：
Aryl halides; Diselenides; Photochemistry; Radical reactions; C-Se bond coupling; DIARYL SELENIDES; DIPHENYL DISELENIDE; CATALYZED SYNTHESIS; CLEAVAGE; IODIDE; BORYLATION; DISULFIDE; CHEMISTRY; ANALOGS;
D O I：
10.1002/adsc.202200042
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
A light-mediated C-Se bond coupling reaction of aryl halides with diselenides under mild photocatalyst-free conditions for preparing aryl selenoethers has been achieved. The transformation is charactered by readily available materials, mild conditions, broad substrate scope and high efficiency. A reasonable mechanism has been proposed based on the preliminary mechanistic investigation. The protocol is also suitable for forging C-S bond and C-Te bond by the use of disulfides and ditellurides.
引用
收藏
页码：1607 / 1612
页数：6
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