Synthesis and characterization of new rhenium-tin complexes with mu(2)eta(3)-bridging CO2 ligands

被引：11
作者：
Gibson, DH [1 ]
Mehta, JM [1 ]
Mashuta, MS [1 ]
Richardson, JF [1 ]
机构：
[1] UNIV LOUISVILLE,CTR CHEM CATALYSIS,LOUISVILLE,KY 40292
来源：
ORGANOMETALLICS | 1997年 / 16卷 / 22期
关键词：
D O I：
10.1021/om970454d
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The synthesis and characterization of CO2-bridged rhenium-tin complexes, Cp*Re(CO)-(NO)(CO2)M (2, M = Sn(Cl)Me-2; 6, M = Sn[(O2C)Re(NO)(CO)Cp*]Me-2) are described; both compounds have been structurally characterized and exhibit different binding modes of the CO2 ligands as well as different coordination numbers for the tin atoms, Comparisons of the DRIFTS data on 2 with analogs involving two transition metals show similar dependence of the v(asym) band position of the CO2 ligand on the coordination geometry at the metal center which binds the carboxyl oxygens.
引用
收藏
页码：4828 / 4832
页数：5
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共 10 条
  • [1] MOSSBAUER AND SINGLE-CRYSTAL X-RAY STUDIES OF POLYMERIC DIMETHYLCHLOROTIN ACETATE
    ALLEN, DW
    NOWELL, IW
    BROOKS, JS
    CLARKSON, RW
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1981, 219 (01) : 29 - 34
  • [2] SIR92 - a program for automatic solution of crystal structures by direct methods
    ALTOMARE, A
    CASCARANO, G
    GIACOVAZZO, G
    GUAGLIARDI, A
    BURLA, MC
    POLIDORI, G
    CAMALLI, M
    [J]. JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1994, 27 : 435 - 435
  • [3] CHARACTERIZATION AND THERMOLYSIS REACTIONS OF CO2-BRIDGED IRON-TIN AND RHENIUM-TIN COMPLEXES - STRUCTURE-REACTIVITY CORRELATIONS
    GIBSON, DH
    YE, M
    SLEADD, BA
    MEHTA, JM
    MBADIKE, OP
    RICHARDSON, JF
    MASHUTA, MS
    [J]. ORGANOMETALLICS, 1995, 14 (03) : 1242 - 1255
  • [4] SYNTHESIS AND CHARACTERIZATION OF CO2-BRIDGED RUTHENIUM-ZIRCONIUM AND RHENIUM-ZIRCONIUM COMPLEXES
    GIBSON, DH
    MEHTA, JM
    SLEADD, BA
    MASHUTA, MS
    RICHARDSON, JF
    [J]. ORGANOMETALLICS, 1995, 14 (10) : 4886 - 4891
  • [5] SYNTHESIS AND CHARACTERIZATION OF CO2-BRIDGED BIMETALLIC COMPOUNDS DERIVED FROM A RHENIUM METALLOCARBOXYLATE - CORRELATION OF IR SPECTRAL DATA WITH COORDINATION GEOMETRY AND BONDING TYPE
    GIBSON, DH
    FRANCO, JO
    MEHTA, JM
    MASHUTA, MS
    RICHARDSON, JF
    [J]. ORGANOMETALLICS, 1995, 14 (11) : 5068 - 5072
  • [6] SYNTHESIS AND CHARACTERIZATION OF RHENIUM METALLOCARBOXYLATES
    GIBSON, DH
    MEHTA, JM
    YE, M
    RICHARDSON, JF
    MASHUTA, MS
    [J]. ORGANOMETALLICS, 1994, 13 (04) : 1070 - 1072
  • [7] The organometallic chemistry of carbon dioxide
    Gibson, DH
    [J]. CHEMICAL REVIEWS, 1996, 96 (06) : 2063 - 2095
  • [8] PI-STABILIZED, YET REACTIVE, HALF-SANDWICH CP-ASTERISK-RU(PR3)X COMPOUNDS - SYNTHESIS, STRUCTURE, AND BONDING
    JOHNSON, TJ
    FOLTING, K
    STREIB, WE
    MARTIN, JD
    HUFFMAN, JC
    JACKSON, SA
    EISENSTEIN, O
    CAULTON, KG
    [J]. INORGANIC CHEMISTRY, 1995, 34 (02) : 488 - 499
  • [9] *MOL STRUCT CORP, 1993, TEXS SINGL CRYST STR
  • [10] STRUCTURAL CHEMISTRY OF ORGANOTIN CARBOXYLATES - A REVIEW OF THE CRYSTALLOGRAPHIC LITERATURE
    TIEKINK, ERT
    [J]. APPLIED ORGANOMETALLIC CHEMISTRY, 1991, 5 (01) : 1 - 23
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