Flotation behavior and mechanism of calcium carbonate polymorphs with sodium oleate as collector

被引：9
作者：
Kuang, Jingzhong [1 ,2 ,3 ]
Wang, Xiaoyuan [2 ]
Yu, Mingming [1 ,2 ]
Yuan, Weiquan [2 ]
Huang, Zheyu [2 ]
Zhang, Shaoyan [2 ]
Xiao, Junjie [2 ]
机构：
[1] Jiangxi Prov Key Lab Min Engn, Ganzhou 341000, Peoples R China
[2] Jiangxi Univ Sci & Technol, Sch Resource & Environm Engn, Ganzhou 341000, Peoples R China
[3] Jiangxi Univ Sci & Technol, Sch Resource & Environm Engn, Kejia Rd 156, Ganzhou 341000, Jiangxi, Peoples R China
来源：
POWDER TECHNOLOGY | 2022年 / 398卷
关键词：
Polymorphism; Calcite; Aragonite; Flotation; Exposed plane; ELECTRONIC-STRUCTURE; CRYSTAL-STRUCTURE; ARAGONITE; MINERALS; ADSORPTION; SURFACES; SORPTION; MORPHOLOGY; SEPARATION; KAOLINITE;
D O I：
10.1016/j.powtec.2021.117040
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
Flotation behavior of calcite and aragonite with a sodium oleate collector was studied. The mechanism for the difference in flotation recovery and kinetics of the two minerals was analyzed via adsorption quantity, microcalorimetry, flotation diffraction method, and calculation of unsaturated bond density on mineral exposed planes. Results showed that the flotation recovery and rate of aragonite was higher than those of calcite. The adsorption quantity and rate of sodium oleate on the surface of aragonite was higher than that with calcite. The adsorption heat of sodium oleate with aragonite was higher than calcite, The order of the unsaturated bond densities of calcium points on the exposed planes of calcite and aragonite were (012)(calcite) > (018)(calcite) > (104)(calcite) > (020)(aragonite) > (111)(aragonite) > (220)(aragonite). The unsaturated bond density of calcium points on the exposed planes of aragonite were less than those of the calcite exposed planes. Sodium oleate could more easily overcome water molecules when it interacted with aragonite. Thus, the flotation recovery and rate of aragonite was higher than that of calcite. (c) 2021 Elsevier B.V. All rights reserved.
引用
收藏
页数：10
相关论文
共 44 条
[1]   Physical and thermal treatment of phosphate ores - An overview [J].
Abouzeid, Abdel-Zaher A. .
INTERNATIONAL JOURNAL OF MINERAL PROCESSING, 2008, 85 (04) :59-84
[2]   Theoretical equilibrium and growth morphology of CaCO3 polymorphs .1. Aragonite [J].
Aquilano, D ;
Rubbo, M ;
Catti, M ;
Pavese, A .
JOURNAL OF CRYSTAL GROWTH, 1997, 182 (1-2) :168-184
[3]   Density functional calculations of the electronic structure and optical properties of aluminosilicate polymorphs (Al2SiO5) [J].
Aryal, Sitaram ;
Rulis, Paul ;
Ching, W. Y. .
AMERICAN MINERALOGIST, 2008, 93 (01) :114-123
[4]   The analysis of crystals by the X-ray spectrometer. [J].
Bragg, WL .
PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-CONTAINING PAPERS OF A MATHEMATICAL AND PHYSICAL CHARACTER, 1914, 89 (613) :468-489
[5]   Discovery of massive seafloor gas seepage along the Wagner Fault, northern Gulf of California [J].
Canet, Caries ;
Maria Prol-Ledesma, Rosa ;
Dando, Paul R. ;
Vazquez-Figueroa, Viridiana ;
Shumilin, Evgueni ;
Birosta, Elisabet ;
Sanchez, Alberto ;
Robinson, Carlos J. ;
Camprubi, Antoni ;
Tauler, Esperanca .
SEDIMENTARY GEOLOGY, 2010, 228 (3-4) :292-303
[6]   A vibrational spectroscopic study of hydrated Fe3+ hydroxyl-sulfates; polymorphic minerals butlerite and parabutlerite [J].
Cejka, Jiri ;
Sejkora, Jiri ;
Plasil, Jakub ;
Bahfenne, Silmarilly ;
Palmer, Sara J. ;
Frost, Ray L. .
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2011, 79 (05) :1356-1363
[7]   DFT calculation on relaxation and electronic structure of sulfide minerals surfaces in presence of H2O molecule [J].
Chen Jian-hua ;
Long Xian-hao ;
Zhao Cui-hua ;
Kang Duan ;
Guo Jin .
JOURNAL OF CENTRAL SOUTH UNIVERSITY, 2014, 21 (10) :3945-3954
[8]   The interaction of flotation reagents with metal ions in mineral surfaces: A perspective from coordination chemistry [J].
Chen, Jianhua .
MINERALS ENGINEERING, 2021, 171
[9]   Effects of surface spatial structures and electronic properties of chalcopyrite and pyrite on Z-200 selectivity [J].
Chen, Jianhua ;
Wang, Jinming ;
Li, Yuqiong ;
Liu, Meng ;
Liu, Yingchao ;
Zhao, Cuihua ;
Cui, Weiyong .
MINERALS ENGINEERING, 2021, 163
[10]   Adsorption of methanoic acid onto the low-index surfaces of calcite and aragonite [J].
Cooper, TG ;
De Leeuw, NH .
MOLECULAR SIMULATION, 2002, 28 (6-7) :539-556
12345