On the mechanism of the perborate oxidation of organic sulfides in glacial acetic acid

被引：0

作者：

Karunakaran, C ^{[1
]}

Kamalam, R ^{[1
]}

机构：

[1] Annamalai Univ, Dept Chem, Annamalai 608002, India

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2000年 / 2000卷 / 19期

关键词：

hydrogen peroxide; organic sulfides; kinetics;

D O I：

10.1002/1099-0690(200010)2000:19<3261::AID-EJOC3261>3.0.CO;2-U

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Perborate solution in glacial acetic acid generates peracetic acid on aging, and the peracetic acid oxidation of organic sulfides is fast. The oxidation with fresh solutions of perborate in acetic acid is smooth and is second order, uncatalyzed by acid; hydrogen peroxide is the oxidizing species. The oxidation conforms to the Exner and Hammett relations.

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页码：3261 / 3263

页数：3

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