Thermal, optical, and electrical properties of gel grown ZMTC

被引:7
作者
Ambujam, K.
Selvakumar, S.
Joseph, Ginson P.
Potheher, I. Vetha
Sagayaraj, P. [1 ]
机构
[1] Loyola Coll, Dept Phys, Madras 600034, Tamil Nadu, India
[2] Queen Marys Coll, Dept Phys, Madras, Tamil Nadu, India
关键词
AC conductivity; dielectric behaviour; FTIR; FT-Raman; gel growth; NLO; optical absorbance; single crystal XRD; thermal stability;
D O I
10.1080/10426910701190766
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The bimetallic thiocyanate of the group IIB divalent d(10) ions Zn2+ and Hg2+ having unique characteristics: The pale color and high thermal stability - Zinc Mercury tetrathiocyanate (ZMTC) is chosen for growth and study. ZMTC is grown in silica gel by chemical reaction method and characterized by single crystal XRD, FTIR, FT-Raman, UV-Vis-NIR, NLO, TGA/DTG, DSC, AC conductivity, and dielectric studies. It has wide transparency window and possesses high second harmonic generation efficiency. Its thermal stability is very high. The dielectric permittivity of this material is very low.
引用
收藏
页码:351 / 356
页数:6
相关论文
共 25 条
  • [1] Growth and surface studies on triglycine sulpho-phosphate (TGSP) single crystals
    Arunmozhi, G
    Kumar, RM
    Jayavel, R
    Subramanian, C
    [J]. MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY, 1997, 49 (03): : 216 - 220
  • [2] BALAREW C, 1984, J SOLID STATE CHEM, V55, P1, DOI 10.1016/0022-4596(84)90240-8
  • [3] BERGMAN JG, 1960, MAT RES B, V5, P913
  • [4] GROWTH OF CADMIUM MERCURY THIOCYANATE AND ZINC MERCURY THIOCYANATE CRYSTALS IN GELS
    BLANK, Z
    [J]. JOURNAL OF CRYSTAL GROWTH, 1973, 18 (03) : 281 - 288
  • [5] Duan XL, 2002, CRYST RES TECHNOL, V37, P446, DOI 10.1002/1521-4079(200205)37:5<446::AID-CRAT446>3.0.CO
  • [6] 2-Q
  • [7] Guo SY, 2001, CRYST RES TECHNOL, V36, P609, DOI 10.1002/1521-4079(200107)36:6<609::AID-CRAT609>3.0.CO
  • [8] 2-J
  • [9] HENISCH HK, 1970, CRYSTAL GROWTH GEL
  • [10] ANALYSIS OF ALTERNATING-CURRENT PROPERTIES OF IONIC CONDUCTORS
    JONSCHER, AK
    [J]. JOURNAL OF MATERIALS SCIENCE, 1978, 13 (03) : 553 - 562