Structural elucidation of the red dye obtained from reaction of 1,8-naphthalenediol with 1,1-diphenylprop-2-yn-1-ol. A correction

被引:5
作者
Carvalho, LM
Silva, AMS
Martins, CI
Coelho, PJ [1 ]
Oliveira-Campos, AMF
机构
[1] Univ Tras Os Montes & Alto Douro, Dept Quim, P-5001911 Vila Real, Portugal
[2] Univ Aveiro, Dept Quim, P-3810193 Aveiro, Portugal
[3] Univ Minho, IBQF, Ctr Quim, P-4700320 Braga, Portugal
关键词
naphthopyrans; 1,8-naphthalenediol; dye; hydrogen-bond;
D O I
10.1016/S0040-4039(03)00118-7
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The structure of the intensely coloured red product obtained through the reaction of 1,8-naphthalenediol with 1,1-diphenylprop-2-yn-1-ol was reinvestigated. Instead of the expected permanent open form of the naphthopyran, the dye presents the alpha,beta-unsaturated chain at a different position of the naphthalene nucleus. The structure of this compound was elucidated on the basis of detailed spectral analysis, including 2D NMR experiments. (C) 2003 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:1903 / 1905
页数:3
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