Hydrothermal synthesis, crystal structure, and magnetic property of a three-dimensional inorganic-organic hybrid material:: Mn(H2O)[HO3PCH2NH(CH2CO2)2]

被引：16

作者：

Fan, Y ^{[1
]}

Li, GH ^{[1
]}

Shi, Z ^{[1
]}

Zhang, D ^{[1
]}

Xu, JN ^{[1
]}

Song, TY ^{[1
]}

Feng, SH ^{[1
]}

机构：

[1] Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Jilin, Peoples R China

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 2004年 / 177卷 / 11期

基金：

中国国家自然科学基金;

关键词：

hydrothermal synthesis; metal phosphonate; structure; property; magnetic susceptibility;

D O I：

10.1016/j.jssc.2004.05.021

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel three-dimensional inorganic organic hybrid compound, Mn(H2O)[HO3PCH2NH(CH2CO2)(2)] from a hydrothermal reaction of Mn (II) ion with N-(phosphonomethyl)iminodiacetic acid (H(4)PMIDA) was reported. The compound crystallizes in the monoclinic P2(1)/n with cell dimensions of a = 5.215(5) Angstrom, b = 14.111(15) Angstrom, c = 12.727(12) Angstrom, beta = 93.646(16)degrees, V = 934.6(16) Angstrom(3), and Z = 4. In this structure each Mn atom is six-coordinated with the carboxylic groups and phosphonic groups to form layers along the bc plane. These layers are further connected with the organic moieties of H(2)PMIDA, resulting in a complicated three-dimensional network structure. Thermogravimetric analysis, IR spectrum and magnetic susceptibility of this compound are given. (C) 2004 Elsevier Inc. All rights reserved.

引用

页码：4346 / 4350

页数：5

共 24 条

[1] New open frameworks based on metal pyridylphosphonates [J].