Facile synthesis of janus "double-concave" tribenzo[a,g,m]coronenes

被引:16
作者
Li, Zhongtao
Lucas, Nigel T.
Wang, Zhaohui [1 ]
Zhu, Daoben
机构
[1] Chinese Acad Sci, Beijing Natl Lab Mol Sci, Key Lab Organ Solids, Inst Chem, Beijing 100080, Peoples R China
[2] Univ Sydney, Sch Chem, Sydney, NSW 2006, Australia
关键词
D O I
10.1021/jo0701029
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
[GRAPHICS] Hexabutoxytribenzo[a,g,m]coronenes have been prepared in three steps from readily accessible hexabutoxytriphenylene. Single-crystal X-ray diffraction analysis reveals that these molecules can adopt an extraordinary "double-concave" conformation that makes them ideal hosts for the binding of different guest molecules at each face.
引用
收藏
页码:3917 / 3920
页数:4
相关论文
共 37 条
[31]  
2-O
[32]   Graphitic molecules with partial "Zig/Zag" periphery [J].
Wang, ZH ;
Tomovic, E ;
Kastler, M ;
Pretsch, R ;
Negri, F ;
Enkelmann, V ;
Müllen, K .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (25) :7794-7795
[33]   Double-Concave graphene:: Permethoxylated hexa-peri-hexabenzocoronene and its cocrystals with hexafluorobenzene and fullerene [J].
Wang, ZH ;
Dötz, F ;
Enkelmann, V ;
Müllen, K .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (08) :1247-1250
[34]   Partially stripped insulated nanowires:: a lightly substituted hexa-peri-hexabenzocoronene-based columnar liquid crystal [J].
Wang, ZH ;
Watson, MD ;
Wu, JS ;
Müllen, K .
CHEMICAL COMMUNICATIONS, 2004, (03) :336-337
[35]   Big is beautiful -: "Aromaticity" revisited from the viewpoint of macromolecular and supramolecular benzene chemistry [J].
Watson, MD ;
Fechtenkötter, A ;
Müllen, K .
CHEMICAL REVIEWS, 2001, 101 (05) :1267-1300
[36]   Molecular wires from contorted aromatic compounds [J].
Xiao, SX ;
Myers, M ;
Miao, Q ;
Sanaur, S ;
Pang, KL ;
Steigerwald, ML ;
Nuckolls, C .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (45) :7390-7394
[37]   Fluorine-substituted hexakisdecyloxy-hexa-peri-hexabenzocoronene [J].
Zhang, Q ;
Prins, P ;
Jones, SC ;
Barlow, S ;
Kondo, T ;
An, ZS ;
Siebbeles, LDA ;
Marder, SR .
ORGANIC LETTERS, 2005, 7 (22) :5019-5022